Fine powders of brushite CaHPO4·2H2O, ardealite Ca(HPO4)x(SO4)1−x·2H2O (Ca(HPO4)0.5(SO4)0.5·2H2O), and calcium sulfate dihydrate CaSO4·2H2O—all containing sodium chloride NaCl as a reaction by-product—were synthesized from 0.5 M aqueous solution CaCl2, hydrophosphate Na2HPO4 and/or Na2SO4. Powder (Ca(HPO4)0.5(SO4)0.5·2H2O) was by precipitation CaCl2 mixed-anionic simultaneously the hydrogen pho...