We report on the intriguing evolution of the dynamical spin correlations of the frustrated spinel ZnMn2O4. Inelastic neutron scattering and magnetization studies reveal that the dynamical correlations at high temperatures are 1D. At lower temperature, these dynamical correlations become 2D. Surprisingly, the dynamical correlations condense into a quasi 2D Ising-like ordered state, making this a...

Spinel-type Li0.64Fe2.15Ge0.21O4, lithium diiron(III) germanium tetra-oxide, has been formed as a by-product during flux growth of an Li-Fe-Ge pyroxene-type material. In the title compound, lithium is ordered on the octa-hedral B sites, while Ge(4+) orders onto the tetra-hedral A sites, and iron distributes over both the octa-hedral and tetra-hedral sites, and is in the trivalent state as deter...

The transformation on heating LiCoMnO4, with a spinel structure, to LiCoMnO3, with a cation-disordered rock salt structure, accompanied by loss of 25% of the oxygen, has been followed using a combination of diffraction, microscopy and spectroscopy techniques. The transformation does not proceed by a topotactic mechanism, even though the spinel and rock salt phases have a similar, cubic close-pa...

Magnetic resonance imaging (MRI) is a powerful clinical imaging technique for the non-invasive diagnosis and posttherapy assessment of a variety of diseases. MRI contrast can be enhanced by the use of positive or negative contrast agents resulting in brighter (T1-weighted) or darker (T2-weighted) images, respectively. Superparamagnetic iron oxide (SPIO) nanoparticles are T2 contrast agents that...

ZnAl2O4 spinel powders were prepared using the Pechini or co-precipitation synthetic route and were then treated at different temperatures (600–1350 °C). These powders were characterised by X-ray diffraction, scanning electron microscopy (SEM), diffuse reflectance and luminescence measurements. SEM investigations and the X-ray patterns showed that the spinel crystallite size was dependent on th...

This work devotes to investigate synthesis and electrical properties of spinel MgCo2O4 that is considered as a candidate of the cathode materials of magnesium-ion batteries in future. Samples were synthesized by two types of techniques: solid-state reaction and wet process. The crystal structures of the samples were analyzed by X-ray diffraction, and their electrical conductivities were obtaine...

ERINGAITE-BEARING ULTRA-REFRACTORY CAI A. N. Krot, K. Nagashima, C. Ma, G. J. Wasserburg. HIGP, U. Hawai‘, USA. CalTech, USA. Introduction: Forsterite-bearing Type B (FoB) Ca,Al-rich inclusions (CAIs) are a rare type of coarse-grained igneous CAIs found almost exclusively in CV3 chondrites [1–5]. Here we describe the mineralogy, petrography, and oxygen-isotope compositions of a FoB CAI Al-2 fro...

Batteries that shuttle multivalent ions such as Mg and Ca ions are promising candidates for achieving higher energy density than available with current Li-ion technology. Finding electrode materials that reversibly store and release these multivalent cations is considered a major challenge for enabling such multivalent battery technology. In this paper, we use recent advances in high-throughput...