Two pathways for biosynthesis of ethylene in higher plants have been postulated (10). One is associated with the breakdown of peroxidized linolenic acid and the other involves the degradation of methionine. Although the formation of ethyilene from peroxidized linolenate has been demonstrated in model systems catalyzed by Cu24, oxygen and ascorbic acid (10) and by an apple extract in the presenc...

reaction between aromatic aldehydes and 3–methyl-1-phenyl-2-pyrazoline-5-one catalyzed by nano-sio2/hclo4 in water under reflux provided a simple and efficient route for the synthesis of 4-((5-hydroxy-3-methyl-1-phenyl-1h-pyrazol-4-yl)(aryl)methyl)-3-methyl-1-phenyl-1h-pyrazol-5-ol derivatives in high yields.

in this work, the effect of ligand's length on interaction energy of six oximes, a [2-(hydroxyimino)-n-((1-(2-(2-((hydroxyimino)methyl)-1h-imidazol-1-yl)ethyl)-1h-1,2,3-triazol-4-yl)methyl)acetamide], b [2-(hydroxyimino)-n-((1-(3-(2-((hydroxyimino)methyl)-1h-imidazol-1-yl)propyl)-1h-1,2,3-triazol-4-yl)methyl)acetamide], c [2-(hydroxyimino)-n-((1-(4-(2-((hydroxyimino)methyl)-1h-imidazol-1-y...

over the past 20 years since tribenuron-methyl herbicide registration in iran, reports of erratic control of broadleaf weeds with it have increased in wheat fields of aq qala. in order to evaluate the incidence of resistance in wild mustard (sinapis arvensis) and turnipweed (rapistrum rugosum) to tribenuron-methyl herbicide, dose-response assays were conducted during the years 1390 and 1391 at ...

In this work, the effect of ligand's length on interaction energy of six oximes, A [2-(hydroxyimino)-N-((1-(2-(2-((hydroxyimino)methyl)-1H-imidazol-1-yl)ethyl)-1H-1,2,3-triazol-4-yl)methyl)acetamide], B [2-(hydroxyimino)-N-((1-(3-(2-((hydroxyimino)methyl)-1H-imidazol-1-yl)propyl)-1H-1,2,3-triazol-4-yl)methyl)acetamide], C [2-(hydroxyimino)-N-((1-(4-(2-((hydroxyimino)methyl)-1H-imidazol-1-yl)but...

The GC-MS profiling of the endogenous oxylipins (Me/TMS) from cucumber (Cucumis sativus L.) leaves, flowers, and fruit peels revealed a remarkable abundance 16-hydroxy-9,12,14-octadecatrienoic acid (16-HOT). Incubations homogenates these organs with α-linolenic yielded 16(S)-hydroperoxide (16-HPOT) as predominant product. Targeted proteomic analyses tissues presence several highly homologous is...

Reaction between aromatic aldehydes and 3–methyl-1-phenyl-2-pyrazoline-5-one catalyzed by nano-SiO2/HClO4 in water under reflux provided a simple and efficient route for the synthesis of 4-((5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)(aryl)methyl)-3-methyl-1-phenyl-1H-pyrazol-5-ol derivatives in high yields.

Methyl tetra - 0-methyl- ?-D- glucopyranoside is stereoselectively prepared from tetramethyl-D- glucopyranose by using (MeI+NaH) in toluene (86%) or cyclohexane (85%), while its ?- isomer is best synthesized in hexamethyl phosphoramide (64%). Similarly, methyl tetra-o-methyl-?- D-mannopyranoside is synthesized in cyclohexane (80%), while its ?- isomer is predominantly prepared by (MeI+n-Bu...

Methylated 2-methyl-2-(4,8,12-trimethyltridecyl)chromans are salinity-sensitive biomarkers that have been detected in immature – early mature petroleum and sediments. In this study, the occurrence distribution patterns of were investigated a set lacustrine sediments from Nördlinger Ries southern Germany marine South China Sea. Among all 2-methyl-2-(4,8,12-trimethyltridecyl)chroman isomers detec...