Selective oxidation of isobutane to methacrolein (MAC) and methacrylic acid (MAA) has received great interest both in the chemical industry academic research. The advantages this reaction originate not only from low cost starting material reduced process complexity, but also limiting use toxic reactants production wastes. Successive studies reports have shown that heteropolycompounds (HPCs) wit...

The morphology of ionic aggregates in semi-crystalline Znand Na-neutralized poly(ethylene-ran-methacrylic acid) (EMAA) ionomer blown films has been explored with scanning transmission electron microscopy (STEM) and small angle x-ray scattering (SAXS). The ionic aggregates of Zn-EMAA are spherical, monodisperse and uniformly-distributed in as-extruded pellets and blown films prepared at low and ...

Hyaluronic acid is a natural polysaccharide found abundantly throughout the body with many desirable properties for application as a biomaterial, including scaffolding for tissue engineering. In this work, hyaluronic acid with molecular weights ranging from 50 to 1100 kDa was modified with methacrylic anhydride and photopolymerized into networks with a wide range of physical properties. With ma...

Immiscible blends of ethylene?propylene?diene?monomer (EPDM) and polyoxymethylene (POM), when EPDM is the major phase were compatibilized on addition an ionomer, poly(ethylene?co?methacrylic acid). The inclusion ionomer reduced interfacial tension between two phases, such that diameter POM domains significantly to 0.5 2 ?m, typical required toughen ductile polymers. mechanical properties result...

A molecularly imprinted polymer (MIP) was synthesized by non-covalent imprinting polymerization using irinotecan as template. Methacrylic acid and 4-vinylpyridine were selected as functional monomers. An optimized procedure coupled to LC-PDA analysis was developed for the selective solid-phase extraction of irinotecan from various organic media. A specific capacity of 0.65 µmol•g-1 for the MIP ...

In this work, molecularly imprinted nanospheres for controlled/sustained release of quercetin were synthesized employing methacrylic acid and ethylene glycoldymethacrylate as functional monomer and crosslinking agent, respectively. One pot precipitation polymerization was chosen as polymerization technique to obtain nanosized materials with spherical shape. Morphological and hydrophilic propert...

The molecular interactions between the component networks in poly(methacrylic acid)/poly(N-isopropyl acrylamide) (PMAA/PNIPAAm) interpenetrating polymer networks (IPNs) were investigated using attenuated total reflectance (ATR)Fourier transform IR (FTIR) spectroscopy. Hydrogen-bond formation was noted between the carboxyl groups of PMAA and the amide groups of PNIPAAm. The ATR-FTIR results show...

THE STRUCTURE OF hydrogel materials can be described as ‘washingline’ polymers. In this analogy the hydrogels are composed of a long backbone (ie the ‘washing line’) from which a variety of chemical groups may be suspended (the ‘washing’). The function of these chemical groups, or monomers, is to attract and bind water. In conventional hydrogel materials, frequently used monomers include Nvinyl...