The lithiation of ferrocenylphosphane Fc-PH(2) (Fc = -C(5)H(4)FeC(5)H(5)) has been reinvestigated and both Fc-PHLi and Fc-PLi(2) have been identified by NMR-spectroscopy. The lithiated phosphanides have been converted to the corresponding mono and bis(silylated) species the latter of which gave synthetic access to an oligomer in which three ferrocene units are symmetrically connected by phospha...

The space charge distribution in low-density polyethylene (LDPE) was measured with the pulsed electroacoustic (PEA) method. We used three types of LDPE: LDPE-L and LDPE-H were prepared by the high pressure process, and m-LDPE was polymerized with a metallocene catalyst. Space charge in LDPE strongly depended upon the electrode material. Semiconductive electrodes enhanced carrier injection into ...

The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl-ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water mol-ecule forms strong O-H⋯O hydrogen bonds with the carb...

Molecules containing the 1H-indene scaffold show a wide range of biological activities, and possess great interest as functional materials, as well as precursors of metallocene complexes as for catalytic polymerization processes. So, several methodologies have been developed for their synthesis. Despite the unquestionable interest of optically active indenes bearing the C-1 as stereogenic cente...

Isotactic poly (1-butene), ipbu-1, was synthesized by using a metallocene catalyst. The thermodynamic phase behavior of polymer–organic solvents systems is very important in every polymer application.  In this paper, the solid–liquid equilibrium of ipbu-1 with different organic solvents (1-heptyne, cyclo octane) was studied by a mathematical model. By considering the experiments temperature...

few novel cobalt(ii) and copper(ii) complexes [m(fmp)3]cl2, [m(fmp)(bpy)2]cl2,[m(fmp)(phen)2]cl2 and [m(fmp)(phen)(bpy)]cl2 (fmp = 3-furan-2-ylmethylene-pentane-2,4-dione, phen = 1,10-phenanthroline, bpy = 2,2'-bipyridine) have been synthesized andcharacterized by elemental analyses, molar conductance, magnetic susceptibility measurements,ir, electronic, epr, mass spectra and cyclic voltam...