نتایج جستجو برای: metal ion complex
تعداد نتایج: 1140454 فیلتر نتایج به سال:
Ferric uptake regulator (Fur) plays a key role in the iron homeostasis of prokaryotes, such as bacterial pathogens, but the molecular mechanisms and structural basis of Fur-DNA binding remain incompletely understood. Here, we report high-resolution structures of Magnetospirillum gryphiswaldense MSR-1 Fur in four different states: apo-Fur, holo-Fur, the Fur-feoAB1 operator complex and the Fur-Ps...
A challenge in molecular spintronics is to control the magnetic coupling between magnetic molecules and magnetic electrodes to build efficient devices. Here we show that the nature of the magnetic ion of anchored metal complexes highly impacts the exchange coupling of the molecules with magnetic substrates. Surface anchoring alters the magnetic anisotropy of the cobalt(II)-containing complex (C...
A proton NMR method for the drtermination of salvation numbers of alkaline earth cations with hexamethyl phosphoramide (HMPA) in nitromethane (NM) as diluents is described. The method is based on monitoring the resonance frequency of HMPA protons as a function of HMPA / metal ion molar ratio at constant metalion concentration. The average salvation number of cations, , at any HMPA / metal ...
Homing endonucleases are site-specific DNA endonucleases that function as mobile genetic elements by introducing double-strand breaks or nicks at defined locations. Of the major families of homing endonucleases, the modular GIY-YIG endonucleases are least understood in terms of mechanism. The GIY-YIG homing endonuclease I-BmoI generates a double-strand break by sequential nicking reactions duri...
Metal complex of pioglitazone hydrochloride (PLZ) drug with Ni(II) ion is synthesized and characterized using analytical data, molar conductance, IR, UV-Vis, magnetic, mass spectral and XRD studies. From the analytical data, the complex is proposed to have general formula [(C 19 H 19 N 2 O 3 S)+ 2 Ni]2Cl-. The conductometric titration using monovariation method reveals that complex is L 2 M typ...
Enzymes are complex macromolecules that catalyze chemical reactions at their active sites. Important information about catalytic interactions is commonly gathered by perturbation or mutation of active site residues that directly contact substrates. However, active sites are engaged in intricate networks of interactions within the overall structure of the macromolecule, and there is a growing bo...
We have previously reported that metal ion binding could restrict the excited state rotation of a biaryl chromophore, suppressing intersystem crossing and leading to increased emission. We have now applied the restriction of excited state dynamics to suppression of the other fundamental nonradiative decay pathway, internal conversion, in biarylacetylenes. This indicates that both nonradiative d...
An extraction-spectrophotometric method for the determination of trace amounts of ammonium ion is described. Ammonium ion is effectively extracted as a neutral ternary complex NH . DB 18C6. calmagite at pH 3.0 into chloroform, followed by spectrophotometric determination at =48 5 nm. Molar absorptivity of the ternary complex at this wavelength is 1.08 10 mol cm . Beer's law is obeyed over...
نمودار تعداد نتایج جستجو در هر سال
با کلیک روی نمودار نتایج را به سال انتشار فیلتر کنید