Many new mixed ligand complexes of mercury(II) have been synthesized with LH = 4,5-(diphenyl)-1,2,4-triazole-3-thione (diptSH) and tertiary phosphines as co-ligands. The compounds characterized by elemental analyses, IR, UV–Vis, molar conductivity, NMR spectroscopy. In the binuclear (2-5), both Hg atoms tetrahedral geometry, atom bonded to three halide ions one thione (LH) through sulfur atom. ...

Nickel(II) complexes have been synthesized and characterized using nuclear magnetic resonance (NMR), infrared spectroscopy, high resolution mass elemental analysis. The were evaluated as pre-catalysts in the direct hydrogenation of furfural to furfuryl alcohol. C1 C4 gave higher conversion (97% 96%, respectively), a result, they also transfer formic acid hydrogen source where (93%) was obtained...

lanthanide(iii) chloro complexes of 4[n-(4’-hydroxy-3’-methoxybenzalidene) amino] antipyrine semicarbazone (hmbaaps) (i) and 4[n-(3’,4’,5’-trimethoxybenzalidene) amino] antipyrine semicarbazone (tmbaaps) (ii) with the general composition lncl3.2l (ln = la, pr, nd, sm, gd, tb, dy or ho; l = hmbaaps or tmbaaps) are reported. all the complexes were synthesized in ethanolic medium and refluxed the ...

background: mercury (hg) is a hazardous metal responsible for environmental contamination and human intoxication. methyl mercury bio-accumulation through food chain can be responsible for chronic mercury exposure of south caspian sea communities with a diet rich in fish. uncertainties about exposure levels that could have damaging consequences for nervous system development of infants makes bio...

abstract studies have shown that birds due to being in the high trophic levels on the ecosystems, and also high sensitivity to toxic substances are a useful indicator for the evaluation of mercury pollution. the objective of the present study was to evaluate mercury level in the feathers of turdus philomelos and turdus merula in khanikan forests as an indicator of mercury contamination. to atta...

on the basis of the some studies recently published on the concentration of potentially dangerous levels of mercury, a global pollutant and highly toxic element in sea fish and specially tuna fish, this work has been carried out to determine the concentration of mercury in canned tuna fish, that compose a large majority of the fish most people eat. for this reason, 30 cans, produced by differen...

the purpose of this study was to evaluate the exposure to mercury (hg), and to examine the various parameters, which contribute to high levels of mercury of iranian dentists in tehran. one-hundred hair samples were collected from dentists. in addition, fifty samples from a control group were taken for comparison. the survey included a structured questionnaire designed to provide information abo...