Transition metal dichalcogenides (TMDCs), such as MoS2 and WSe2, are free of dangling bonds and therefore make more "ideal" Schottky junctions than bulk semiconductors, which produce Fermi energy pinning and recombination centers at the interface with bulk metals, inhibiting charge transfer. Here, we observe a more than 10× enhancement in the indirect band gap photoluminescence of transition me...

objective: shear bond strength is an important property inherent to the durability of tooth-colored restorative materials namely composite resins. it has been years that halogen light sources have been used for polymerization of composite resins. in recent years light emitting diodes (led) have been introduced for this purpose. with respect to their longer bulb life, needless of a filter and no...

Carbon nanotube (CNT) and metal nanoparticle (NP) assemblies are conjugated nanosystems with potential applications in catalysis, sensing, and light harvesting. Due to poor solubility of CNTs, previously reported synthetic approaches are limited to large multi-walled CNTs, bundles of single-walled CNTs (SWNTs), or surface-bound CNTs. Here we report a solution-phase synthesis of SWNT-metal NP as...

Fig. I Lomb i incidenco incidenc irchers in the behavioral and visual sciences The upper panel of Figure 1 shows the output of a tly need a source of monochromatic light whose Bausch and Lomb 641-nm interference filter at five Lgth can be varied. The purpose of this note is different angles of incidence. The peak wavelength of ribe principles and construction of a reliable the distribution move...

A novel strategy was developed to synthesize polymer-coated metal nanoparticles (NPs) through reduction of metal cations with 3,4-dihydroxyphenylalanine (DOPA)-containing polyethylene glycol (PEG) polymers. Catechol redox chemistry was used to both synthesize metal NPs and simultaneously form a cross-linked shell of PEG polymers on their surfaces. DOPA reduced gold and silver cations into neutr...

"Rainbow trapping" has been proposed as a scheme for localized storage of broadband electromagnetic radiation in metamaterials and plasmonic heterostructures. Here, we articulate the dispersion and power flow characteristics of rainbow trapping structures, and show that tapered waveguide structures composed of dielectric core and metal cladding are best suited for light trapping. A metal-insula...

A graphene oxide-terpyridine conjugate (GOTC) based colorimetric and fluorescent nano-chemosensor was synthesized. It showed high selectivity and sensitivity for Fe2+ and Fe3+ ions in neutral aqueous solution over other metal ions such as Li+, Na+, Ba2+, Ca2+, Al3+, Cd2+, Co2+, Cu2+, Hg2+, Mn...

Introduction: This in vitro study investigates the marginal and internal fit of indirect class II composite restorations. Two different processes for chair-side restorations were compared. In group A, the restorations were fabricated using CAD/CAM technology (Cerec, Sirona, Germany, Bernsheim) and in group B they were made by hand (GrandioSO Inlay System, VOCO GmbH, Germany, Cuxhaven). Methods:...

The development of efficient catalytic systems for direct aromatic C-H bond functionalization is a long-desired goal of chemists, because these protocols provide environmental friendly and waste-reducing alternatives to classical methodologies for C-C and C-heteroatom bond formation. A key challenge for these transformations is the reoxidation of the in situ generated metal hydride or low-valen...