High-throughput ab initio calculations, cluster expansion techniques, and thermodynamic modeling have been synergistically combined to characterize the binodal and the spinodal decompositions features in the pseudo-binary lead chalcogenides PbSe-PbTe, PbS-PbTe, and PbS-PbSe. While our results agree with the available experimental data, our consolute temperatures substantially improve with respe...

BACKGROUND Male infertility is affected by several factors. Lead is one of the heavy metals more bioavailable than usually modifies the sperm quality in humans. OBJECTIVE The aim of this study was to establish the role of lead in semen quality in environmentally exposed men. MATERIALS AND METHODS Semen and blood samples were obtained from two groups: the exposed group (EG=20) and the non-ex...

Sulfide is a common product of marine anaerobic respiration, and a potent reactant biologically and geochemically. Here we demonstrate the impact on microbial communities with the removal of sulfide via electrochemical methods. The use of differential pulse voltammetry revealed that the oxidation of soluble sulfide was seen at +30 mV (vs. SHE) at all pH ranges tested (from pH = 4 to 8), while n...

Phytoene synthase (Psy) and Phytoene desaturase (Pds) are the first two regulatory enzymes in the carotenoids biosynthetic pathway. The genes Psy and Pds are under transcriptional control in many photosynthetic organisms. In the present study, using quantitative real time- PCR (qRT-PCR), the effects of uncoated and gum-Arabic coated PbS nanoparticles (GA-coated PbS NPs) and light intensity on t...

Herein, an ultrasound-assisted dispersive magnetic micro-solid phase extraction (DM-?SPE) approach, along with electrothermal atomic absorption spectrometry (ETAAS) for the determination of lead at trace level in spring, well, river mineral and tap water samples was developed. The step is based on synthesis PbS, following sonochemical decomposition L-cysteine used as sulphide precursor its anch...

Quantum Dot Solar Cells In article number 2202994, Yana Vaynzof and co-workers report on a strategy to eliminate excess lead halide species from the interdot spacing of sulfide quantum dot solar cells. This process significantly enhances coupling, resulting in improved efficiency stability photovoltaic devices.

In sediments that contain iron monosulfide, cadmium, nickel, lead, zinc, and silver(I) form insoluble metal sulfides that lower the metal ion activity in the sediment-pore water system, thereby reducing toxicity. However, metal sulfides are susceptible to oxidation by molecular oxygen resulting in metal solubilization. To better understand the sources and sinks of metal sulfides in sediments, i...

A screen of the Saccharomyces cerevisiae deletion strain set was performed to identify genes affecting hydrogen sulfide (H(2)S) production. Mutants were screened using two assays: colony color on BiGGY agar, which detects the basal level of sulfite reductase activity, and production of H(2)S in a synthetic juice medium using lead acetate detection of free sulfide in the headspace. A total of 88...

The nonsteroidal anti-inflammatory drug (NSAID) sulindac prevents experimental colon cancer and can regress precancerous polyps in humans. Sulindac sulfide inhibits cyclooxygenase (COX)-mediated prostaglandin synthesis and retards the growth of cultured colon cell lines primarily by inducing apoptosis. Given the known role of mitogen-activated protein kinase (MAPK) in signal transduction and th...