Isothermal melt crystallization kinetics of PVDF was investigated by differential scanning calorimetry. Thin PVDF film has been fabricated by the solvent casting technique using dimethylformamide (DMF). Then, the samples were melted and subsequently crystallized in the range of the crystallization temperature (Tc) between 138 and 145 °C. The crystallization kinetics was derived from Avrami equa...

based on driving force for crystallization of one-component gas hydrate, in this report an expression for the supersaturation for crystallization of multicomponent gas hydrate is derived. expressions for the supersaturation are obtained in isothermal and isobaric regimes. the results obtained are applied to the crystallization of hydrates of mixtures of methane plus ethane and can apply to othe...

Crystallization of an isotactic polypropylene (iPP) homopolymer and two propylene/ethylene random copolymers (RACO), induced by high-stress shear, was studied using in situ synchrotron wide-angle X-ray diffraction (WAXD) at 137 °C. The “depth sectioning” method (Fernandez-Ballester, Journal of Rheology 53:5 (2009), pp. 1229−1254) was applied in order to isolate the contributions of different la...

In this work, low-cost and high permeation NaA zeolite membrane was successfully prepared on kaolinite support by in-situ crystallization using secondary growth method. The effect of synthesis conditions including temperature time crystallization, water ratio studied aiming to improve the quality performance membrane. thoroughly characterized many techniques such as X-ray diffraction, scanning ...

transparent glasses in a system of li2o-mgo-sio2-al2o3-fchemical constituents were prepared by melt quenching method. in the fabrication of nanocrystal glass-ceramics, controlled nucleation and subsequent crystal growth were necessary to avoid loss of transparency. it was therefore important to understand thermal properties and crystallization kinetics of the glass ceramics. the crystallization...

In this study, the crystallization behavior of oriented isotactic polypropylene during solid-state stretching was investigated by in-situ wide-angle X-ray scattering. Results showed that a new arc appeared on (040) reflection with previous arcs remained when direction inclined to initial orientation direction, as result induced crystallization. The process occurred later than yielding but earli...

The X-CHIP (X-ray Crystallization High-throughput Integrated Platform) is a novel microchip that has been developed to combine multiple steps of the crystallographic pipeline from crystallization to diffraction data collection on a single device to streamline the entire process. The system has been designed for crystallization condition screening, visual crystal inspection, initial X-ray screen...

background: flat urothelial lesions comprise a spectrum of morphologic changes ranging from reactive atypia to carcinoma in situ (cis). urothelial dysplasia and cis are associated with the recurrence and progression of urothelial carcinoma. distinguishing cis and dysplasia from reactive atypia based on histolopathogical features alone is often difficult. using different immunohistochemical mark...

knowledge of the orientation of horizontal in situ stresses is important to some areas of oil and gas field development plans. borehole breakouts observed in image logs and drilling-induced fractures are the main parameters for the determination of the stresses’ directions in situ. in this work, the orientations of borehole breakouts were investigated as a function of depth in oil wells a and b...

the present study deals with development of a floating in-situ gel of the narrow absorption window drug baclofen. sodium alginate-based in-situ gelling systems were prepared by dissolving various concentrations of sodium alginate in deionized water, to which varying concentrations of drug and calcium bicarbonate were added. fourier transform infrared spectroscopy (ftir) and differential scannin...