The reaction of cyanoacetylhydrazine with chloroacetone gave the N-(1-chloropropan-2-ylidene)-2-cyanoacetohydrazide. This compound reacted with either hydrazine hydrate or phenylhydrazine to give the corresponding 1,2,4-triazine derivatives. On the other hand, its reaction with either benzenediazonium chloride or benzaldehyde gave in each case the 1,3,4-oxadiazine derivatives. Moreover, the rea...

ZnO nanorods have been successfully synthesized by a simple microwave-assisted solution phase approach. Hydrazine hydrate has been used as a mineralizer instead of sodium hydroxide. XRD and FESEM have been used to characterize the product. The FESEM images show that the diameter of the nanorods fall in the range of about 25–75 nm and length in the range of 500–1,500 nm with an aspect ratio of a...

An automatic procedure for calibration in continuous-flow systems is proposed. A flow gradient unit in the sample channel, controlled via a switching valve, delivers a concentration gradient of the standard so that the standard concentration varies with time after the flow-rate gradient is started. Thus, the signal (absorbance)- concentration relationship can be determined and checked for (reca...

The title compound, C(17)H(19)N(3)O(3)S, crystallizes with two closely similar independent mol-ecules related by a pseudotranslation of c/2. Each mol-ecule consists of three approximately planar moieties centred on the N(2)CS group and the two ring systems. The packing involves classical H bonds of the form N(amide)-H⋯S and N(hydrazine)-H⋯OC, together with various weak hydrogen bonds and N(hydr...

Phthalimide reacted with phenacyl bromide under microwave irradiation to yield phenacyl isoindolidene-1,3-dione (3b), while 3a reacted with phenylhydrazine to yield the phenylhydrazone 4 that was readily converted into indoylphthalimide 8. Similarly N-benzotriazolylacetone (6a) reacted with phenyl hydrazine to yield the phenylhydrazone 7a that was converted into indoylbenzotriazole 9. Treatment...

-The introduction of artificial +b/3 stacking faults into well-crystallized kaolinite by intercalating and removing hydrazine had no observable effect on the solid-state 29Si nuclear magnetic resonance spectrum of kaolinite. Also, the introduction of such stacking faults did not alter the hydroxyl-stretching region of the infrared spectrum, implying no change in the hydrogen bonding between the...

In peptide synthesis, hydrazides are important intermediates for the azide coupling method. A hydrazide is converted to the corresponding azide in the presence of an acid and a nitrite. When acetic acid (or formic acid) is used as the acid, partial acetylation (or formylation) of the hydrazide occurs as a side reaction. Formylation of the hydrazide is much faster than acetylation. Removal of th...

Azalactone 1 can be synthesized via treatment of 4chlorobenzoyl glycine with p-anisaldehyde in the presence of acetic anhydride and sod Acetate. The behaviour of azalactone 1 towards nitrogen nucleophiles, for example, anthranilic acid, 6-aminopyrimidin-2,4-dione and 2-amino-6-phenyl 1,3,4thiadiazole can be investigated. Benzoxazone 2 can be treated with hydrazine hydrate, hydroxylamine hydroch...

The aim of this paper is to emphasize the studies carried out for the new generation of hydrazine pump s, in terms of modeling, control and experiments in order to optimize the use of gas. It consists of an actuator conception for which it is possible to move the hydrazine pump leading to very short required displacements. It may be shown that the main advantage in using these new devices is th...

Treatment of O-acyl lipids with hydrazine degrades them to hydrazides of the constituent fatty acids. These hydrazides react with acetone to yield less polar and more volatile N'-isopropylidenealkanohydrazides, R-CO-NH-N = C(CH3)2, which strongly absorb ultraviolet light and are amenable to thin-layer and gas-liquid chromatographic analyses. In presence of cyclopentene, reduction of double bond...