In this work, we show for the first time that high-silica zeolites (MFI, TON, MTT, and *MRE) could be synthesized from a combined strategy of both zeolite seeding alcohol filling in absence organic structure-directing agents (OSDAs). High-silica ZSM-5 with Si/Al ratios ranging 38 to 240 (TF-Al-ZSM-5) via route. The key success technique was employment an aluminosilicate precursor fully 4-coordi...

The Front Cover shows a symbolic rocket. main structure of the rocket represents ZSM-5 zeolite, and boosters represent added Ga Cr species, respectively. This picture means that propane is rapidly converted into propene hydrogen on modified then BTX aromatics. In their Full Paper, B. Xu et al. introduced to Ga/ZSM-5 catalyst by tuning impregnation sequence amount. Plenty Cr3+ species strong int...

The application of neutron scattering techniques (inelastic scattering, quasi-elastic and diffraction) to explore concepts connected with the methanol-to-hydrocarbon reaction over zeolite ZSM-5 are considered. Reproduced from [ Cat. Sci. Tech. , 2018, 8 3304–3312] under a Creative Commons Attribution Licence (CC-BY).

One-dimensional medium-pore zeolites are promising catalysts for propylene production from naphtha cracking due to their high selectivity. However, fast deactivation pore mouth blockage is preventing these being widely used in commercial applications. In this study, we molecular dynamics simulations investigate the diffusion of three one-dimensional aluminosilicate frameworks (ZSM-23, ZSM-22, Z...

This article reviews recently published work showing how inelastic neutron scattering spectroscopy can be used to identify species found in zeolite ZSM-5 as a catalyst for conversion of methanol hydrocarbons. The advantages and disadvantages the technique are illustrated, current challenges identified.

Self-di!usion in zeolites is studied using a simple mean-"eld theory and dynamic Monte-Carlo simulations of di!usion on a lattice model of the zeolite pore space. Our method is powerful, because of its simplicity, #exibility and ability to study the in#uence of various factors: the topology of the pore network, the fraction of strong adsorption sites, the relative strengths of weak and strong s...

Zeolite catalysis is determined by a combination of pore architecture and Brønsted acidity. As Brønsted acid sites are formed by the substitution of AlO4 for SiO4 tetrahedra, it is of utmost importance to have information on the number as well as the location and neighbouring sites of framework aluminium. Unfortunately, such detailed information has not yet been obtained, mainly due to the lack...

Two NMR techniques, zH MAS NMR and echo Fourier 27AI NMR, have been applied for the first time to the investigation of Bronsted sites in dehydrated hydrogen forms ofzeolites. The “AI signal of SiOHAl sites, which was “NMR-invisible” until now, yields a quadrupole coupling constant C,,= 16 MHz for the dehydrated zeolite H-ZSM-5. The values of C,, determined from the ZH MAS NMR spectra of SiODAl ...

Kaolin with alumina and silica content is used as the main material in this research to study synthesis of ZSM-5 zeolite. The hydrothermal process was carried out through different aging times, namely 12, 24 36 hours. Tetrapropyl ammonium bromide (TPABr) a template for Mobile Five-1 (MFI) structure guide. X-ray diffraction (XRD) infrared spectroscopy (FTIR) instruments were characterize zeolite...