OBJECTIVE The purpose of this study was to measure the micro-tensile bond strength (microTBS) of two adhesives to dentin and to correlate this microTBS with the micro-tensile fracture strength (microTFS) of primer-adhesive mixtures of the two adhesives. METHODS The three-step etch&rinse adhesive OptiBond FL (Kerr) and the two-step self-etch adhesive Clearfil SE Bond (Kuraray) were used to bon...

Vibrational spectra of two gaseous cations having NH···O intramolecular ionic hydrogen bonds and of nine protonated di- and polyamines having NH···N internal proton bridges, recorded using IR Multiple Photon Dissociation (IRMPD) of mass-selected ions, are reported. The band positions of hydroxyl stretching frequencies do not shift when a protonated amine becomes hydrogen bonded to oxygen. In th...

in this paper, the hydrogen bonding (hb) effects on the nmr chemical shifts of selected atoms in serineand serine-nh2o complexes (from one to ten water molecules) have been investigated with quantummechanical calculations of the 15n and 13c tensors. interaction with water molecules causes importantchanges in geometry and electronic structure of serine.for the compound studied, the most importan...

Raman spectra of ice VII and X were investigated using strong plasma shockwave generated by laser-induced breakdown (LIB) in liquid water. Simultaneously, the occurrence of the hydrogen emission lines of 656 nm (Hα), 486 nm (Hβ), 434 nm (Hγ) and 410 nm (Hδ) was observed. At 5 × 10(12) W/cm(2) optical power density, the O-H symmetric stretching, translational and librational modes of ice VII and...

Ultraviolet resonance Raman (UVRR) spectroscopy has been used to characterize the structure and hydrogen bonding state of the distal histidine (His42) in horseradish peroxidase (HRP) complexed with carbon monoxide (HRP-CO). The HRP-CO - HRP UVRR difference spectrum in D(2)O solution at pD 7.0 shows two positive peaks at 1408 and 1388 cm(-)(1), which are ascribable to medium-to-weak and strong h...

This study evaluated physical and mechanical properties of experimental strandboard panels with random flake alignment manufactured from eastern redcedar (Juniperus virginiana L.) logs. Panels were made at two density levels of 0.65 g/cm and 0.78 g/cm using phenol formaldehyde adhesive applied at a rate of 8%. Mechanical properties including modulus of elasticity and modulus of rupture, and int...

and CH3COOH) and hydrogen bond vibrations due to both hydroxyl groups of CH3COOH and water molecules. The main spectral feature in the (OH) stretching mode region is the appearance of two broad bands at about 2500 and 1950 cm–1, designated as (AB) and C bands, respectively. The presence of ABC bands with their frequency positions and intensities as well as the OH and OH frequencies are spectros...

background: failures such as marginal discoloration and composite chipping are still the problems of tooth-colored restorations on the substrate of enamel and porcelain, which some of these problems are consequently as a result of failures in the bonding layer. using fi lled resin has been recently introduced to increase the bond strength of this layer. the aim of this study was to compare the ...