Under ambient conditions, water freezes to either hexagonal ice or a hexagonal/cubic composite ice. The presence of hydrophobic guest molecules introduces a competing pathway: gas hydrate formation, with the guests in clathrate cages. Here, the pathways of the phase transitions are sought as sequences of states with coexisting phases, using a generalized replica exchange algorithm designed to s...

Ocean storage of CO2 was proposed by Marchetti as one of greenhouse gas control technologies, where CO2 is captured from flue gas of fossil fuels and injected into deep seafloor below the depth of 3500m to be sequestered from the atmosphere as shown in Fig. 1. In the last decade of the twenties century, there was a great progress in study on the ocean storage. Aya and his colleagues and Nishika...

Clathrate hydrates are crystalline compounds formed by a physically stable interaction between water and relatively small guest molecules. Under suitable conditions of guest pressure and temperature, water molecules, via hydrogen bonds, form into polyhedral cavities that connect to give space-filling frameworks. Because of partial cage filling, these crystalline compounds are nonstoichiometric....

Formation of hydrates is observed during drilling and construction of wells, more frequently in gas wells located offshore (deep sea water). Hydrates of natural gas can clog chokes and kill lines, and obstruct the opening or closure of blow out preventer (BOP), seal well override valve and immobilize well string. Because of that, this work was mainly focused in the selection and adaptation of a...

We present a model of the global methane inventory as hydrate and bubbles below the sea floor. The model predicts the inventory of CH(4) in the ocean today to be approximately 1600-2,000 Pg of C. Most of the hydrate in the model is in the Pacific, in large part because lower oxygen levels enhance the preservation of organic carbon. Because the oxygen concentration today may be different from th...

Natural gas hydrate accumulations were confirmed in the Dongsha Area of the South China Sea by the Guangzhou Marine Geological Survey 2 (GMGS2) scientific drilling expedition in 2013. The drilling sites of GMGS2-01, -04, -05, -07, -08, -09, -11, -12, and -16 verified the existence of a hydrate-bearing layer. In this work gas production behavior was evaluated at GMGS2-8 by numerical simulation. ...

Electrical methods offer a potential geophysical approach to determining the sub-bottom distribution of gas hydrate in the deep marine environment. Gas hydrate is essentially nonconductive. Hence, sediments with pore spaces partially filled with hydrate or containing veins filled with hydrate are more resistive than surrounding sediments with pore spaces filled with seawater. To date, attempts ...

6 A two-dimensional model of a passive continental margin was adapted to 7 the simulation of the methane cycle on Siberian continental shelf and 8 slope, attempting to account for the impacts of glacial / interglacial 9 cycles in sea level, alternately exposing the continental shelf to freezing 10 conditions with deep permafrost formation during glacial times, and 11 immersion in the ocean in i...

The kinetics of film growth of hydrates of methane, ethane, and methane-ethane mixtures were studied by exposing a single gas bubble to water. The morphologies, lateral growth rates, and thicknesses of the hydrate films were measured for various gas compositions and degrees of subcooling. A variety of hydrate film textures was revealed. The kinetics of two-dimensional film growth was inferred f...