Two hydroxy-functionalized hyper-cross-linked ultra-microporous compounds have been synthesized by Friedel-Crafts alkylation reaction and characterised with different spectroscopic techniques. Both compounds exhibit an efficient carbon dioxide uptake over other gases like N2, H2 and O2 at room temperature. A high isosteric heat of adsorption (Qst) has been obtained for both materials because of...

Abstract When an atomic-size break junction is mechanically stretched, the total conductance of the contact remains approximately constant over a wide range of elongations, although at the same time the transmissions of the individual channels (valence orbitals of the junction atom) undergo strong variations. We propose a microscopic explanation of this phenomenon, based on Coulomb correlation ...