Nucleation and growth kinetics give valuable information about the crystal growth process, which can be employed in the growth of large size crystals. Accordingly, this paper discusses nucleation theory as applied to crystallizing negative solubility lithium sulphate monohydrate (LSMH) crystal. Solubility, metastable zone and induction period values were determined experimentally in order to op...

Efficient and accurate path-sensitive analyses pose the challenges of: (a) analyzing an exponentially-increasing number of paths in a control-flow graph (CFG), and (b) checking feasibility of paths in a CFG. We address these challenges by introducing an equivalence relation on the CFG paths to partition them into equivalence classes. It is then sufficient to perform analysis on these equivalenc...

Thin polymer films have striking dynamical properties that differ from their bulk counterparts. With the simple geometry of a stepped polymer film on a substrate, we probe mobility above and below the glass transition temperature Tg. Above Tg the entire film flows, whereas below Tg only the near-surface region responds to the excess interfacial energy. An analytical thin-film model for flow lim...

This paper reports on the measurement of elastic modulus of thin film materials by a magnetostrictive sensor. Thin film materials of Cu, Cr, Al, Au, Sn, In, Au-rich lead free solder (AuSn) and SiC were sputter deposited onto well defined strips of Metglas sensor. The elastic modulus of the thin film materials was determined by measuring the resonant frequency of the sensors before and after fil...

Despite extensive efforts, a definitive picture of the glass transition of ultra-thin polymer films has yet to emerge. The effect of film thickness h on the glass transition temperature T(g) has been widely examined, but this characterization does not account for the fragility of glass-formation, which quantifies how rapidly relaxation times vary with temperature T. Accordingly, we simulate sup...

Adsorption of water on a thin silica film grown on a Mo(112) single crystal was studied by temperatureprogrammed desorption, infrared reflection absorption spectroscopy, and photoelectron spectroscopy using synchrotron radiation. Water does not dissociate on the defect-free oxygen-terminated silica surface. In contrast to adsorption at 100 K, where water follows a zero-order desorption kinetics...

The surface of a thin liquid film with a nonconstant curvature is unstable, as the Laplace pressure drives a flow mediated by viscosity. We present the results of experiments on one of the simplest variable curvature surfaces: a thin polymer film with a step. Height profiles are measured as a function of time for a variety of molecular weights. The evolution of the profiles is shown to be self-...

In a previous experimental study on free-standing silicon thin film, it was observed that cleavage front transmission across a through-thickness grain boundary could be considerably constrained by film surfaces. As a result, the boundary toughness was much lower than its bulk counterpart. In this study, inspired by the observation of crack front behaviors at triple grain boundary junctions, we ...

Wrinkling modes are determined for a two-layer system comprised of a neo-Hookean film bonded to an infinitely deep neo-Hookean substrate with the entire bilayer undergoing compression. The full range of the film/substrate modulus ratio is considered from the limit of a traction-free homogeneous substrate to very stiff films on compliant substrates. The role of substrate prestretch is considered...

An alternative indium-free material for transparent conducting oxides of fluorine-doped tin oxide [FTO] thin films deposited on polyethylene terephthalate [PET] was prepared by electron cyclotron resonance - metal organic chemical vapor deposition [ECR-MOCVD]. One of the essential issues regarding metal oxide film deposition is the sheet resistance uniformity of the film. Variations in process ...