UNLABELLED Iron and copper toxicity has been presumed to involve the formation of hydroxyl radical (*OH) from H2O2 in the Fenton reaction. The aim of this study was to verify that Fe2+-O2 and Cu+-O2 chemistry is capable of generating *OH in the quasi physiological environment of Krebs-Henseleit buffer (KH), and to compare the ability of the Fe2+-O2 system and of the Fenton system (Fe2+ + H2O2) ...

A recently developed Pd-based electro-Fenton (E-Fenton) process enables efficient in situ remediation of organic contaminants in groundwater. In the process, H₂O₂, Fe(II), and acidic conditions (~pH 3) are produced in situ to facilitate the decontamination, but the role of ubiquitous natural organic matters (NOM) remain unclear. This study investigated the effect of Aldrich humic acid (HA) on t...

Combining ultrasonic irradiation and the Fenton process as a sono-Fenton process, chemical oxygen demand (COD) in refinery wastewater was successfully eliminated using response surface methodology (RSM) with central composite design (CCD). The impact of two main influential operational parameters (iron dosage reaction time) on COD removal from generated by an Iraqi petroleum facility explored. ...

Reactive oxygen species are involved in many diseases where the radical species OH, peroxynitrite and the non-radical, hypochlorous acid, play an outstanding role. The formation of OH-type oxidants is essentially confined to a few types of reactions. The most prominent ones are the one-electron reduction of hydrogen peroxide by F2+ or Cu+ -ions (Fenton-type reactions), reaction of hypochlorite ...

Background: Pharmaceuticals have arisen as emerging environmental pollutants due to their potential impact on humans, animals and microorganisms even at low concentrations. Conventional wastewater treatment plants are known to be ineffective for removal of many pharmaceuticals present in wastewater. Advanced oxidation processes are one of the most promising treatment technologies for degradatio...

In order to see the influence of different variable parameters (initial pH of the solution, Fe++ concentration and H2O2 concentration) and the efficiency to remove Malachite Green dye (Basic Green 4) from aqueous solution, Fenton Oxidation method was employed. Then different parameters were studied using known concentration (150 mg/l) and initial COD (256 mg/l) of prepared dye synthetic solutio...

diazinon pesticide and its metabolites have been identified in aquatic systems worldwide. it was related to toxicity for aquatic organisms, animals, and humans. waters contaminated with such persistent insecticides should be treated with suitable treatment processes. in this research, diazinon removal from aqueous solutions by the photo–fenton–like process (uv/h2o2/fe0) was investigated. this e...