We study the adsorption behavior of Ga on ~0001! GaN surfaces combining experimental specular reflection high-energy electron diffraction with theoretical investigations in the framework of a kinetic model for adsorption and ab initio calculations of energy parameters. Based on the experimental results we find that for substrate temperatures and Ga fluxes typically used in molecular-beam epitax...

Copper is present in different types of industrial effluents, being responsible for environmental pollution. Biosorption of heavy metals can be an effective process for the removal and recovery of heavy metal ions from aqueous solutions. The biomass of marine algae has been reported to have high uptake capacities for a number of heavy metal ions. In this paper, the adsorption properties of a pr...

background & aims of the study: heavy metals discharge to environment is a worldwide problem growing in scale. when they accumulate in the environment and in food chains, they can profoundly disrupt biological processes. peganum harmala seeds (phs) was used as a bio-sorbent, using a continuous system for removing pb2+, co2+, ni2+ and cu2+ ions from aqueous solutions. materials and methods: phs ...

The potential of water hyacinth ash for phenol adsorption from aqueous solution was studied. Batch kinetic and isotherm studies were carried out under varying experimental conditions of contact time, phenol concentration, adsorbent dosage and pH. The adsorption of phenol decreased with increasing pH. The Freundlich and Langmuir adsorption models were used for the mathematical description of ads...

Batch sorption experiments were carried out to remove As(III) from aqueous solution by using iron based commercial adsorbent Bayoxide. The effects of various experimental parameters, such as initial concentration, contact time and solution pH on the adsorption of As(III) on adsorbent was investigated. The adsorption density increased with increased initial arsenic concentration and contact time...

Polyacrylonitrile (PAN)-oxime-nano Fe2O3 was used as an adsorbent for the removal of fluoride from water. The influences of contact time, initial fluoride concentration, and adsorbent dosage were investigated by batch equilibrium studies. The rate of adsorption was rapid with equilibrium being attained after 100min. The Langmuir isotherm model was found to represent the measured adsorption data...

The kinetics and mechanisms of molybdate adsorption/desorption at the g-Al2O3/water interface were studied by using the pressure-jump apparatus with conductivity detection at 298 K. A double relaxation was observed due to the adsorption/desorption process. Adsorption data and triple-layer model (TLM) simulation results suggest the formation of both monoand bidentate innersphere complexes (SMoO4...

ABSTRACT: Excess fluoride ion (F) in drinking water causes harmful effects such as dental and skeletal fluorosis. Hence, its concentration in drinking water must not exceed a certain range. This study investigated the removal of F from aqueous solutions with CuO nanoparticles using a range of experimental approaches, including pH, adsorbent dose, contact times, and initial F concentration. The ...

The present study presents the effective use of nanocrystalline akaganeite for the adsorption of an anionic (SDS), a cationic (CTAB), and a nonionic (tween80) surfactant from wastewater. Equilibrium experiments, as well as thermodynamic analysis, were performed. The maximum SDS adsorption occurs at the lowest pH value (5), the opposite is observed for CTAB (pH = 11), while for tween80, the chan...

Copper is one of the most dangerous pollutants that require removal from wastewater effluents before being discharged. Here are reported on the adsorption performance of a novel environmental friendly material, calcium alginate gel beads as a non-conventional technique for the successful removal of copper ions from aqueous solution. Batch equilibrium studies were carried out to evaluate the ads...