Using infrared spectroscopy, we show that spin self-organization in untwinned La2-xSrxCuO4 (LSCO) crystals has profound consequences for the dynamical conductivity sigma(omega). The electronic response of CuO2 planes acquires significant anisotropy in the spin ordered state with enhancement of the conductivity along the direction of the diagonal spin stripes by up to a factor of 2. An examinati...

Infrared reflectance measurements were made on the single crystal pyrochlore Cd2Os2O7 in order to examine the transformations of the electronic structure and crystal lattice across the boundary of the metal-insulator transition ~MIT! at TMIT5226 K. All predicted IR active phonons are observed in the conductivity over all temperatures and the oscillator strength is found to be temperature indepe...

Mixed ionic-electronic conductors are widely used in devices for energy conversion and storage. Grain boundaries in these materials have nanoscale spatial dimensions, which can generate substantial resistance to ionic transport due to dopant segregation. Here, we report the concept of targeted phase formation in a Ce0.8Gd0.2O2-δ-CoFe2O4 composite that serves to enhance the grain boundary ionic ...

Charge density wave (CDW), the periodic modulation of the electronic charge density, will open a gap on the Fermi surface that commonly leads to decreased or vanishing conductivity. On the other hand superconductivity, a commonly believed competing order, features a Fermi surface gap that results in infinite conductivity. Here we report that superconductivity emerges upon Se doping in CDW condu...

Electroreduction of CO2 into hydrocarbons could contribute to alleviating energy crisis and global warming. However, conventional electrocatalysts usually suffer from low energetic efficiency and poor durability. Herein, atomic layers for transition-metal oxides are proposed to address these problems through offering an ultralarge fraction of active sites, high electronic conductivity, and supe...

Hexagonal manganites, h-RMnO3 (R=Sc, Y, Ho-Lu), have been intensively studied for their multiferroic properties, magnetoelectric coupling, topological defects and electrically conducting domain walls. Although point defects strongly affect the conductivity of transition metal oxides, the defect chemistry of h-RMnO3 has received little attention. We use a combination of experiments and first pri...

Demonstration of a tunable conductivity of the LaAlO(3)/SrTiO(3) interfaces drew significant attention to the development of oxide electronic structures where electronic confinement can be reduced to the nanometer range. While the mechanisms for the conductivity modulation are quite different and include metal-insulator phase transition and surface charge writing, generally it is implied that t...

Interfaces and boundaries in condensed-matter systems often have electronic properties distinct from the bulk material and thus have become a topic of both fundamental scientific interest and technological importance. Here we identify, using microwave impedance microscopy, enhanced conductivity of charge-order domain walls in the layered manganite Pr(Sr0.1Ca0.9)2Mn2O7. We obtain a complete meso...

A detailed description of the electronic properties, chemical state, and structure of uniform single and few-layered graphene oxide (GO) thin films at different stages of reduction is reported. The residual oxygen content and structure of GO are monitored and these chemical and structural characteristics are correlated to electronic properties of the thin films at various stages of reduction. I...

Inelastic electron process that leads to vibrational excitation has attracted much attention of since the conductivity of molecules bridging the electrodes is found to be strongly affected when they are vibrationally excited [1]. Considering that the conduction electrons passes through the electronic state crossing the Fermi level or hopping through the HOMO or LUMO state of the molecule, the e...