The elements carbon and boron uniquely form extensive series of compounds with hydrogen; hydrocarbons and boron hydrides. In comparison to carbon, which forms various chainor ring-like structures, boron, an electron deficient element, forms quasi-aromatic clusters architecturally derivable from a twelve-vertex icosahedral unit. Herein, we focus on a comparison of hydrocarbon and boron hydride b...

A bacterium was isolated by elective culture with p-hydroxybenzoate as substrate and nitrate as electron acceptor. It grew either aerobically or anaerobically, by nitrate respiration, on a range of aromatic compounds. The organism was identified as a pseudomonad and was given the trivial name Pseudomonas PN-1. Benzoate and p-hydroxybenzoate were metabolized aerobically via protocatechuate, foll...

A mild and versatile one-pot synthesis of core-expanded naphthalene diimides has been developed, which undergoes a nucleophilic aromatic substitution reaction and then an imidization reaction, allowing an easy and low-cost access to diverse n-type organic materials. Some newly synthesized compounds by this one-pot operation exhibited high electron mobility of up to 0.70 cm(2) V(-1) s(-1) in amb...

Aromatic cation activation is a useful strategy to promote deoxyfunctionalization; however, the deoxyfluorination of alcohols with cyclopropenium cation remains an unsolved problem due to the weak nucleophilicity of fluoride ion. Here we report the use of 3,3-difluoro-1,2-diarylcyclopropenes (CpFluors) as easily accessible and reactivity-tunable deoxyfluorination reagents. The electronic nature...

A series of novel hybrid compounds between dihydrobenzofuran and imidazole has been prepared and evaluated in vitro against a panel of human tumor cell lines. The results suggest that substitution of the imidazolyl-1-position with an electron-donating dihydrobenzofuran, and the imidazolyl-3-position with a naphthylacyl or electron-rich phenacyl group, were vital for modulating cytotoxic activity.

Background and objectives: Herbal aromatic waters are one of the products used in the Iranian traditional medicine. These products have small amount of essential oil. The purpose of this study was to identify the effective substances of herbal aromatic waters by various techniques (GC/FID and GC/MS). It is hoped that with assessment of these compounds by mentioned techniques a ...

Inverse-electron-demand Diels–Alder (IEDDA) reactions of electron-poor 2-pyrones as electrophilic dienes have been extensively studied in the past fifty years. These provide an efficient access to bridged bicyclic lactones and their derivatives, such densely functionalized 1,3-cyclohexadienes after CO2 extrusion polysubstituted aromatic compounds through elimination. This reaction has used for ...

Genus Origanum is an aromatic plant used in folk medicine and as a culinary herb, whose composition of volatile compounds is influenced by the type of species and geographical locations. This research evaluates the effect of altitude on the composition of volatile compounds and the contents of carvacrol and thymol of Origanum x majoricum Cambess and Origanum majorana L. fi...

A soil bacterium, Pseudomonas sp. strain P136, was isolated by selective enrichment for anaerobic utilization of o-phthalate through nitrate respiration. o-Phthalate, m-phthalate, p-phthalate, benzoate, cyclohex-1-ene-carboxylate, and cyclohex-3-ene-carboxylate were utilized by this strain under both aerobic and anaerobic conditions. m-Hydroxybenzoate and p-hydroxybenzoate were utilized only un...