A bifunctional probe (FecNC), containing a recognition part and an electrochemical active center, was applied to electrochemical detection of GG mismatch duplexes. The preparation of gold electrodes modified by mismatch and complementatry duplexes was characterized by electrochemical impedance spectroscopy (EIS) and optimized for better detection in terms of self-assembly time, hybridization ti...

An electrochemical device, which consists of electrode arrays, nanocavities, and microwells, was developed for multi-electrochemical detection with high sensitivity. A local redox cycling-based electrochemical (LRC-EC) system was used for multi-electrochemical detection and signal amplification. The LRC-EC system consists of n(2) sensors with only 2n bonding pads for external connection. The na...

Silicon materials remain unused for supercapacitors due to extreme reactivity of silicon with electrolytes. However, doped silicon materials boast a low mass density, excellent conductivity, a controllably etched nanoporous structure, and combined earth abundance and technological presence appealing to diverse energy storage frameworks. Here, we demonstrate a universal route to transform porous...

even though the use of enzymes as useful analytical reagents when immobilized onto a transducer such as an electrochemical device has been reported in the literature for nearly two decades, the direct, i.e. unmediated electrochemistry of enzymes is, nevertheless, a rather recent development. efforts will be made to introduce the fundamental basis for protein-surface interactions with emphasis o...

background: the poly-allyl diglycol carbonate (padc) detector is of particular interest for development of a fast neutron dosimeter. fast neutrons interact with the constituents of the cr-39 detector and produce h, c and o recoils, as well as (n, α) reaction. these neutron- induced charged particles contribute towards the response of cr-39 detectors. material and methods: electrochemical etchin...

By means of an extended center-manifold reduction, we derive the nonlocal complex Ginzburg-Landau equation (NCGLE) valid for electrochemical systems with migration coupling. We carry out the stability analysis of the uniform oscillation, elucidating the role of the nonlocal coupling in electrochemical systems at the vicinity of a supercritical Hopf bifurcation. We apply the NCGLE to an experime...

this review reports recent advances in metallic nanostructures based electrochemical sensors. interesting aspects of nps include size and shape-dependent interatomic bond distances, melting points, chemical reactivity, and optical and electronic properties. the small size of metallic nanostructures has allowed nanoscale electrochemical processes to be probed. electrochemical characteristics can...

Development of an in situ technique for measuring electrochemical impedance spectra in real time during an electrochemical experiment is described. The technique is based on staircase voltammetry with relatively large step heights, in which a series of increasing potential steps are applied to an electrochemical system, and the resulting currents are sampled. The first derivatives of the curren...

Single nanoparticle (NP) electrochemical measurements are widely described, both theoretically and experimentally, as they enable visualization of the electrochemical signal of a single NP that is masked in ensemble measurements. However, investigating the behavior of individual NPs using electrochemical signals remains a significant challenge. Here we report experiments and simulations demonst...

Among numerous active electrode materials, nickel hydroxide is a promising electrode in electrochemical capacitors. Nickel hydroxide research has thus far focused on the crystalline rather than the amorphous phase, despite the impressive electrochemical properties of the latter, which includes an improved electrochemical efficiency due to disorder. Here we demonstrate high-performance electroch...