Nuclear Magnetic Resonance (NMR) spectroscopy has made a tremendous impact in many areas of chemistry, biology and medicine. In this report a student-oriented approach is presented, which enhances the ability of students to comprehend the basic concepts of NMR spectroscopy and the NMR spectra of various nuclei. The origin of chemical shifts, coupling constants, spin relaxation and the Nuclear O...

The present work introduces a new three-dimensional nuclear magnetic resonance ~3D NMR! experiment for the analysis of half-integer quadrupolar nuclei in solids. The method is based on the multi-rank expansion of the high-field NMR Hamiltonian governing the central transition of these spins in terms of irreducible spherical tensor elements. This approach leads to a temporal spin evolution given...

water soluble chitosan oligosaccharide (cho) was hydrophobically modified with camptothecin (cpt) in different molar ratios of cpt, and characterized by ft-ir and 1 h-nmr spectroscopy. nanomicelles prepared by these copolymers were analyzed for size, zeta, and length of time they remain stable. the critical micelle concentration (cmc) and dissociation of micelles at physiological ph and acidic ...

tetrahydrobenzo[b]pyran derivatives 1 were utilized for the synthesis of several new pyrano[2,3-d]pyrimidine derivatives 2. compound 2 was obtained in the presence of ac2o/h2so4 (as a catalyst) and was confirmed by spectroscopic data such as ir, 1h nmr and 13c nmr. ab initio calculation was carried out to study geometric optimization, thermodynamic parameters, aromaticity and dynamic process of...