The dinuclear title compound, [Pb(2)(C(6)H(8)O(4))(NO(3))(2)(C(19)H(13)N(5))(2)], lies with the mid-point of the butyl chain of the bridging adipate unit on a center of inversion. The Pb(II) ion is covalently bonded to the nitrate anion and is bonded to a carboxyl-ate group of the adipate unit by another covalent bond. The N-heterocycle functions in a chelating tridentate mode. The metal atom e...

Biological catalysis frequently causes changes in noncovalent bonding. By building on Pauling's assertion that any long-lived, chemically distinct interaction is a chemical bond, this article redefines enzyme catalysis as the facilitated making and/or breaking of chemical bonds, not just of covalent bonds. It is also argued that nearly every ATPase or GTPase is misnamed as a hydrolase and actua...

The aim of this study was to compare the bond strengths of three self-etching materials during one year of storage. Clearfil SE Bond (SE), Clearfil Protect Bond (PB), and Clearfil Tri-S Bond (TS) were used for bonding to dentin and enamel according to manufacturer's instructions. Microshear bond strength values were measured after 24 hours, six months, and one year. Two-way ANOVA showed that th...

The Front Cover shows a captivating image of two gears intricately interlocking and merging into one another. Metaphorically, gear represents the concept free aluminylene, while other embodies diverse boron Lewis acids. As these unite, they give rise to distinct forms aluminum−boron-bonded compounds. One variant encompasses an aluminum−boron electron-sharing bond, manifests dative bond. This di...

In this paper, I will look at the rather convoluted discovery process which gave birth to the concept of the shared electron pair bond as developed by G.N. Lewis, to be subsequently appropriated by the American founders of quantum chemistry, and highlight the complex relations between conceptual development and the different contexts in which ideas are created and presented. I will show how the...

Halogen bond donors had an increasing impact on catalysis in recent years, and their development is highly active. In particular, numerous iodine-based halogen have been developed used to promote various reactions through coordinating carbonyl groups, a ubiquitous mode of activation catalysis. We now report computational data which strongly suggests that alternative mode, direct π-complexation,...

PURPOSE The aim of this study was to evaluate microbial contamination and inhibitory effect against Streptococcus mutans (SM) of Prime & Bond (PB), Single Bond (SB) and Excite (EX) bonding systems before use, and after 10 and 20 applications. METHODS The bonding material was collected by applying a drop of the material directly on broth brain-heart infusion. The samples were homogenized, dilu...

The aim of this study was to determine microtensile bond strength of two and one-step self-etching adhesive systems to dentin. 25 intact human third molars were used. Flat surfaces of mid-coronal dentin were exposed and the teeth were divided into 5 groups (n=5). Composite build-ups were made using the following self-etching systems / composite materials: 2-step self-etching system Contax / Ecu...

AIM This study tested the null hypothesis that there is no difference on microleakage of dentin-bordered composite restorations using single or double coats of adhesive from one-bottle adhesive systems. METHODS AND MATERIALS The enamel surface was removed from freshly extracted bovine teeth, and standardized Class V cavities (3 x 3 x 1.5 mm) were made at the cervical areas of buccal surfaces....