نتایج جستجو برای: cymene xylene

تعداد نتایج: 3670  

Journal: :Revista Brasileira de Farmacognosia 2011

2008
Hakan Arslan Don VanDerveer İsmail Özdemir Nevin Gürbüz Yetkin Gök Bekir Çetinkaya

The asymmetric unit of the title compound, (C(14)H(17)N(2)S(2))[Ru(C(10)H(14))Cl(3)], contains a 1,3-bis-(thio-phen-2-ylmeth-yl)-3,4,5,6-tetra-hydro-pyrimidinium cation and a trichlorido(η(6)-p-cymene)ruthenate(II) anion. The Ru atom exhibits a distorted octa-hedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three chloride atoms occupying the ot...

2011
M Mahboubi N Kazempour

BACKGROUND AND OBJECTIVES The aim of this study was to evaluate the chemical composition and antimicrobial activity of Satureja hortensis and Trachyspermum copticum essential oils against different kinds of microorganisms in vitro. MATERIAL AND METHODS The antimicrobial activity was evaluated by micro broth dilution assay and the chemical composition of essential oils was analyzed by GC and G...

Journal: :Dalton transactions 2016
Divambal Appavoo Nandhagopal Raja Robert Deschenaux Bruno Therrien Diego Carnevale

The hydrogen-bonded arene ruthenium metalla-rectangle, [(p-cymene)2Ru2(OO∩OO)(UPy)2]2(4+), obtained from 1-(4-oxo-6-undecyl-1,4-dihydropyrimidin-2-yl)-3-(pyridin-4-ylmethyl)urea (UPy) and the dinuclear arene ruthenium clip (p-cymene)2Ru2(OO∩OO)Cl2 (OO∩OO = 2,5-dioxido-1,4-benzoquinonato), is investigated by means of solution-phase NMR spectroscopy. Rotating frame nuclear Overhauser effect measu...

Journal: :Zeitschrift fur Naturforschung. C, Journal of biosciences 2008
Harminder Pal Singh Shalinder Kaur Sunil Mittal Daizy R Batish Ravinder K Kohli

The phytotoxicity of the three major monoterpene constituents of the essential oil from leaves of Artemisia scoparia Waldst. & Kit. (redstem wormwood) was investigated. GC/GC-MS analysis revealed that the essential oil (yield 0.84%) is a complex mixture containing 19 monoterpenes, 7 sesquiterpenes and 15 other compounds--aliphatic alcohols, ketones, aromatic hydrocarbons and esters. The three m...

Journal: :Dalton transactions 2010
Nicolas P E Barry Olivier Zava Julien Furrer Paul J Dyson Bruno Therrien

Cationic tetranuclear and hexanuclear opened metalla-assemblies incorporating 5,15-bis(4-pyridyl)-10,20-diphenylporphyrin (bpp) or 5,10,15-tris(4-pyridyl)-20-phenylporphyrin (tpp) panels and dinuclear arene ruthenium clips [(p-cymene)(2)Ru(2)(OO[intersection]OO)(2)](2+) (OO[intersection]OO = oxalato, 2,5-dioxydo-1,4-benzoquinonato (dobq)) have been assembled in the presence of silver triflate. ...

2010
Yannick Borguet Xavier Sauvage Guillermo Zaragoza Albert Demonceau Lionel Delaude

The tandem catalysis of ring-closing metathesis/atom transfer radical reactions was investigated with the homobimetallic ruthenium-indenylidene complex [(p-cymene)Ru(μ-Cl)₃RuCl(3-phenyl-1-indenylidene)(PCy₃)] (1) to generate active species in situ. The two catalytic processes were first carried out independently in a case study before the whole sequence was optimized and applied to the synthesi...

2013
T. Sarma R. K. Bhola

Ruthenium complexes are an object of great attention in the field of medicinal chemistry because of their selective antimetastatic properties and low systemic toxicity in comparison to cisplatin, the widely used antitumor drug. Ruthenium-para-cymene-μ-O-dichloride, a newly synthesised Ruthenium compound was used against Dalton’s lymphoma in vivo and in vitro to examine the cytotoxicity of the d...

Journal: :Dalton transactions 2016
Anaïs Pitto-Barry Amy South Alison Rodger Nicolas P E Barry

The functionalisation of the 16-electron complex [Os(η(6)-p-cymene)(1,2-dicarba-closo-dodecarborane-1,2-dithiolato)] (1) with a series of Lewis bases to give the 18-electron complexes of general formula [Os(η(6)-p-cymene)(1,2-dicarba-closo-dodecarborane-1,2-dithiolato)(L)] (L = pyridine (2), 4-dimethylaminopyridine (3), 4-cyanopyridine (4), 4-methoxypyridine (5), pyrazine (6), pyridazine (7), 4...

Journal: :Molecules 2016
Pavel Štarha Zdeněk Trávníček Radka Křikavová Zdeněk Dvořák

Halogenido and carboxylato Ru(II) half-sandwich complexes of the general composition [Ru(η⁶-p-cym)(dpa)X]PF₆ (1-5) were prepared and thoroughly characterized with various techniques (e.g., mass spectrometry, NMR spectroscopy and X-ray analysis); dpa = 2,2'-dipyridylamine; p-cym = p-cymene; X = Cl- (for 1), Br- (for 2), I- (for 3), valproate(1-) (for 4) or 4-phenylbutyrate(1-) (for 5). A single-...

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