Voltammetric detection of biological molecules was carried out using chopped carbon fibers produced from carbon fiber reinforced plastics that are biocompatible and inexpensive. Because chopped carbon fibers normally are covered with a sizing agent, they are difficult to use as an electrode. However, when the surface of a chopped carbon fiber was treated with ethanol and hydrochloric acid, it b...

The Langmuir-Blodgett (L-B) technique is used to coat electrode surfaces with bifunctional monolayer films that are designed to carry out two functions: passivation and gating. We demonstrate that incorporation of ubiquinone (Q50) in otherwise passivating L-B monolayer films allows us to control access to the electrode surface via a controlled number of single molecule gate sites. The electrode...

Nitrogen (N) and sulfur (S) co-doped activated graphene (N,S-AGR) was prepared by the one-pot pyrolysis of a mixture of graphene oxide (GO), thiourea, and potassium hydroxide (KOH), where thiourea acts as the source of N and S dopants and KOH is the activator for porosity. N,S-AGR with a dopant abundance of 2.8 at% N and 2.3 at% S was then used as a high-activity electrocatalyst in the fabricat...

A new sensor constructed by a platinum electrode coated with a non-plasticized poly(acrylamide) polymer (PAA) film coupled with phthalocyaninato tin(II) ([Sn(II)(pc)]) was developed. The potentiometric response behavior of this PAA-[Sn(II)(pc)] electrode for such anions as CN-, F-, Cl-, and Br- in dimethylacetamide and acetonitrile were investigated. The electrode showed a Nernstian response to...

A voltammetric-amperometric detector for liquid chromatography based on a dual electrode electrochem-ical cell has been developed. This detector enables voltammograms to be obtained without the charging current problems inherent in single electrode voltammetric detectors. The detector is operated by scanning the potential of the upstream (voltammetric) electrode and detecting the electrolysis p...

In this work, preparation of a molecularly imprinted polymer (MIP) film and its recognition properties for sulfamethoxazolewere investigated. The overoxidized polypyrrole (OPPy) film was prepared by the cyclic voltammetric deposition of pyrrole (Py) in the presence of supporting electrolyte (tetrabutylammonium perchlorate-TBAP) with and without a template molecule (sulfamethoxazole) on a pencil...

Diphenylpyraline hydrochloride (Di-HCl) has been determined in raw material and its pharmaceutical preparation Eskornade capsule (5mg/capsule) using differential pulse voltammetry (DPV) and conductimetric determination. It was found that Di-HCl gives a characteristic cyclic voltammetric (CV) and differential pulse voltammetric (DPV) peak in acetonitrile using platinum and glassy carbon sensors ...

The purpose of this study was the determination kinetic regularities methionine electrooxidation process on Pt(Pt) electrode in an aqueous-alkaline medium.The main anion were determined using by methods cyclic voltammetry, coulometry, and electrochemical impedance spectroscopy. concentration alkaline solution before after anodic oxidation spectrophotometrically spectrophotometer UNICO 2800. mea...

A new differential pulse voltammetric method for the determination of clozapine in drug dosage forms has been described. In this study, amount commercial determined at bismuth modified glassy carbon electrode by taking advantage electrochemical oxidation it. The was with BiCl3 to prepare film electrode. acetate buffer solution pH = 5.00 selected as supporting electrolyte where maximum current o...

Chemically produced coppercontaining MnO2 nanoparticles were studied using FTIR, UV-Vis spectroscopy, XRD, AFM, cyclic voltammetric and charge/discharge behaviour. Mixed nanocomposites have a crystalline size of 50 nm was calculated through Debye Scherrer’s equation from XRD analysis. The FTIR spectra recorded region 400- 4000 cm-1, clean doped Manganese dioxide nanoparticles. Mn–O can be ascri...