Twelve P-chiral phosphine oxides were screened for their ability to act as a chiral Lewis base catalyst for the asymmetric hydrosilylation of ketimines, providing chiral amines in good conversion and yield, but relatively poor enantioselectivity (ee <30%). Mechanistic studies paralleling work on chiral sulfinamides have shown a non-linear relationship of catalyst enantioselectivity and the chir...

Four lectures about chiral symmetry and dynamical fermions in QCD. 1) Chiral symmetry in continuum QCD with an eye toward lattice simulations. 2) Lattice fermions with exact chiral symmetry: staggered fermions, fermions in five dimensions, chiral fermions in four dimensions. 3) A typical lattice simulation from beginning to end: the simulation algorithm, designing observables to measure some de...

We review the recent development of chiral sum frequency generation (SFG) spectroscopy and its applications to study chiral vibrational structures at interfaces. This review summarizes observations of chiral SFG signals from various molecular systems and describes the molecular origins of chiral SFG response. It focuses on the chiral vibrational structures of proteins and presents the chiral SF...

We use a cluster algorithm to study the critical behavior of strongly coupled lattice QCD in the chiral limit. We show that the finite temperature chiral phase transition belongs to the O(2) universality class as expected. When we compute the finite size effects of the chiral susceptibility in the low temperature phase close to the transition, we find clear evidence for chiral singularities pre...

The electrochemically driven transfer of the chiral anions of Dand L-tryptophan across the interface water/chiral liquid (Dor Lmenthol) is stereoselective, and it can be used to determine quantitatively the difference in Gibbs energies for the solvation of chiral ions in chiral liquids. The ion transfer can be achieved in a three-phase arrangement where a droplet of the chiral liquid containing...

Three topics about the application of quenched chiral perturbation theory to matter fields are studied. It is proved that the hairpin axial current couplings in quenched chiral perturbation theories do not contribute to the quenched chiral singularities for one chiral loop renormalization of matter field properties. The modification of mass corrections in the chiral limit due to nonzero mass sp...

According to the Nielsen-Ninomiya No-Go theorem, the doubling of fermions on the lattice cannot be suppressed in a chiral theory. Whereas Wilson and staggered fermions suppress doublers with explicit breaking of chiral symmetry, the random lattice does so by spontaneous chiral symmetry breaking even in the free theory. I present results for meson masses, the chiral condensate and fermionic eige...

Developing of alternative chiral thiol stabilizers from the assembly of achiral thiol (e.g. thioglycolic acid) and chiral ligand (e.g. arginine) via both hydrogen bonding and electrostatic interactions was proposed and successfully applied to an efficient preparation of chiral CdS quantum dots (QDs). Chiral CdS QDs capped mainly with achiral thioglycolic acid were also obtained that may allow t...

We extend the theory of chiral and factorization algebras, developed for curves by Beilinson and Drinfeld in [BD1], to higher-dimensional varieties. This extension entails the development of the homotopy theory of chiral and factorization structures, in a sense analogous to Quillen’s homotopy theory of differential graded Lie algebras. We prove the equivalence of higherdimensional chiral and fa...

We analyze the quark mass dependence of the Roper mass to one-loop order in relativistic baryon chiral perturbation theory. The loop integrals are evaluated using infrared regu-larization which preserves chiral symmetry and establishes a chiral counting scheme. The derived chiral expansion of the Roper mass may prove useful for chiral extrapolations of lattice data. For couplings of natural siz...