The charge redistribution upon photoexcitation is investigated for a series of pyrene photoacids to better understand the driving force behind excited-state proton-transfer processes. The changes in electric dipole for the lowest two electronic transitions ( (1)L b and (1)L a) are measured by Stark spectroscopy, and the magnitudes of charge transfer of the protonated and deprotonated states are...

The linear filters characterized by a state-variable realization given by matrices with nonnegative entries (called positive filters) are heavily restricted in their achievable performance. Nevertheless, such filters are the only choice when dealing with the charged coupled device MOS technology of charge routing networks (CRN’s), since nonnegativity is a consequence of the underlying physical ...

Measurements of electron transfer rates as well as of charge transport characteristics in DNA produced a number of seemingly contradictory results, ranging from insulating behaviour to the suggestion that DNA is an efficient medium for charge transport. Among other factors, environmental effects appear to play a crucial role in determining the effectivity of charge propagation along the double ...

We report on an experimental study of the charge transfer dynamics in a P3HT : PCBM blend by means of a femtosecond fluorescence up-conversion technique. Using two-photon excitation we probe the exciton dynamics in P3HT and a P3HT : PCBM blend with a weight ratio of 1 : 1 at excitation densities of up to 6 × 1018 cm−3. In both samples we find strongly nonexponential decay traces compatible with...

We show that whenever an electron transfers between closed-shell molecular fragments, the exact correlation potential of time-dependent density functional theory develops a step and peak structure in the bonding region. This structure has a density dependence that is nonlocal both in space and in time that even the exact adiabatic ground-state exchange-correlation functional fails to capture it...

A microphysical mechanism that may be important in the electrification of thunderstorms is probed in an experimental study of collisional charging of ice surfaces. The study examined mass and charge transfer in single collisions between two ice samples and their dependence on growth, temperature, impact strength, and time delay between impacts. The polarity is consistent with earlier esults in ...

The linear filters characterized by a state-variable realization given by matrices with nonnegative entries (called positive filters) are heavily restricted in their achievable performance. Nevertheless, such filters are the only choice when dealing with the charged coupled device MOS technology of charge routing networks (CRNs), because nonnegativity is a consequence of the underlying physical...

We explore the relationship between grand canonical (GC) ensemble and charge equilibration (CE), also known as electronegativity equalization, theories for describing charge flow in molecules. We introduce a new unifying approach to classical charge transfer theories based on valence bond (VB) theory and the maximum entropy (ME) method, which we call MEVB. We show how MEVB reduces to GC and CE ...