A technique for the fabrication of bacterial cellulose-based films with CeO2 nanofiller has been developed. The structural and morphological characteristics materials have studied, their thermal mechanical properties in dry swollen states having determined. preparation methodology makes it possible to obtain composites a uniform distribution nanoparticles. catalytic effect ceria, regarding oxid...

in this work, polypyrrole/ceo2 nanocomposite (nc) was synthesized in the presence of methylorange as a reactive self-degraded soft template. the field emission scanning electron microscopy(fesem) images indicate that the ceo2 nps have a nucleus effect and cause a homogenous ppycore–shell type morphology with an encapsulation of the ceo2 core by the ppy shell. the effect ofnc on acrylic waterbor...

CeO2 nanooctahedrons, nanorods, and nanocubes were prepared by the hydrothermal method and were then used as supports of Cu-based catalysts for the water-gas shift (WGS) reaction. The chemical and physical properties of these catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), N2 adsorption/desorption, UV-Vis spectroscopy, X-ray photoelectron spectro...

Although homogeneity at the atomic level of CeO2-ZrO2 with a Ce/Zr atomic ratio close to unity is considered to be one of the main causes for the increased total oxygen storage capacity (OSC), the characterization approaches of homogeneity remain a major challenge. We propose a simple, yet effective method, to assess both structural and compositional homogeneity of CeO2-ZrO2 by using Eu(3+) lum...

In this work, nickel-based electrodes were prepared using composite electrodeposition technique in a nickel sulphamate bath containing suspended microor nano-sized CeO2 particles. The prepared NieCeO2 composite electrodes exhibit an enhanced high catalytic activity toward hydrogen evolution reaction (HER) in alkaline solutions. X-ray diffraction patterns indicated that the CeO2 particles have b...

Hydrogenation of cyclohexanecarboxamide to aminomethylcyclohexane was conducted with silica-supported bimetallic catalysts composed of noble metal and group 6-7 elements. The combination of rhodium and molybdenum with molar ratio of 1:1 showed the highest activity. The effect of addition of various metal oxides was investigated on the catalysis of Rh-MoO x /SiO2, and the addition of CeO2 much i...

We present a study of the electrical properties of insulating CeO2 layers in combination with superconducting ~Y/Dy! Ba2Cu3O72d ~RBCO! films over ramps and in crossover structures. CeO2 is frequently used as a buffer layer, or template layer for biepitaxial grain boundary junctions, but can also be used as an insulating layer in ramp-type junctions and other multilayer structures. Epitaxial thi...

The amount of oxygen storage and release from catalysts on a millisecond scale (MS-OSC) is believed to play an essential role in automotive three-way catalysts. We have developed a new method to evaluate the MS-OSC based on the rapid detection of reaction products on catalyst surfaces immediately after CO and O2 injections using pulsed valves by time-of-flight mass spectrometry. CO and O2 were ...