Conventionally, methane is reformed into syngas, and subsequently converted into C1-oxygenates (methanol and formaldehyde). A novel option is the catalyst-free single-step conversion of methane to C1-oxygenates. This study presents a comprehensive model of methane partial oxidation to formaldehyde as an intermediate chemical species in methane oxidation process using microreactor. The dependenc...

We measured proteasome activities and the levels of proteasome subunits in dermal fibroblasts from individuals aged 20-82 years. Proteasome activities changed with age in a biphasic manner, decreasing significantly up to 50 years of age and showing no significant change between 50 and 78 years of age. Similarly, proteasome activities in replicatively senescent dermal fibroblasts showed a passag...

The perovskite-type oxide catalyst LaFe1-xCuxO3 (x=0, 0.1, 0.2) was prepared by the sol–gel method, and tested as a catalyst in the wet aerobic oxidation (WAO) of lignin into aromatic aldehydes. The lignin conversion and the yield of each aromatic aldehyde were significantly enhanced in the catalytic process, compared with the non-catalyzed process. Moreover, it was shown that the stability of ...

Pervaporation membrane reactors are ideal candidates to enhance conversion in reversible reactions generating water as a by-product. This equilibrium displacement can be enhanced through close integration of reaction and separation by way of catalytic membranes. In this research, catalytic hollow fibre pervaporation membranes for the close integration of reaction and separation will be develope...

Computational fluid dynamic (CFD) modeling of full-scale catalytic converters with realistic chemistry has remained elusive primarily due to the extreme computational requirements. In this work, a new low-memory coupled implicit solver, based on the conservative unstructured finite-volume method, was utilized to simulate laboratory-scale catalytic converters with implicit coupling between fluid...