In this study, preparation of nano-sized gamma alumina with high specific surface area and high yield by thereaction between aluminum nitrate and sodium carbonate, without using any surfactant is reported. Bohemite (Aluminum oxyhydroxide) was prepared as a precursor by strict control of pH and reaction temperature. The gel produced was purified by washing fol...

The samples of spent chlorinated Pt/Al2O3 catalysts that were used in the isomerization process were decoked at elevated temperatures under airflow and different oxygen concentrations. The surface of the catalyst was characterized by thermal gravimetric analysis, differential scanning calorimetry, Brunauer-Emmett-Teller analysis, attenuated total reflection fast Fourier in...

In this paper, Fe3O4-chitosan nanoparticles were prepared by the immobilization of chitosan on the surface of Fe3O4 nanoparticles. Then, the 5-substituted hydantoins were synthesized from the condensation of aldehyde derivatives, ammonium carbonate and zinc cyanide as a well-known cyanating agent by the magnetic Fe3O4-chitosan nanoparticles under neat conditions. Fe3O4-Chitosan nanocatalyst as ...

H3PW12O40 (PW12) was immobilized over mesoporous alumina through the reaction of mesoporous alumina functionalized 3-aminopropyl triethoxy silane (3-APTES) and PW12. The surface properties of the functionalized nanocomposite was analyzed by a series of characterization techniques like elemental analysis, FTIR and XRD. XRD and adsorption–desorption analysis shows that the mesostructure of silica...

During the last 20 years, surface scientists have developed a variety of techniques that make it possible to study, on the molecular level, the structure, composition, and chemical bonding in the surface monolayer. Both single-crystal model catalysts and real catalyst systems that are active in important chemical processes have been investigated by a combination of ultrahigh-vacuum surface scie...

NO reduction by CO was investigated over a AuPd(1 0 0) model catalyst at near atmospheric pressures. The alloy catalyst exhibits higher CO2 formation rates below 550 K than does pure Pd, although the binding energy of NO on the alloy surface is substantially less, i.e., its dissociation tendency is much less, compared with pure Pd. This behavior is rationalized by the fact that the low CO/NO-bi...

In this paper, Fe3O4-chitosan nanoparticles were prepared by the immobilization of chitosan on the surface of Fe3O4 nanoparticles. Then, the 5-substituted hydantoins were synthesized from the condensation of aldehyde derivatives, ammonium carbonate and zinc cyanide as a well-known cyanating agent by the magnetic Fe3O4-chitosan nanoparticles under neat conditions. Fe3O4-Chitosan nanocatalyst as ...