Nanoparticulate zero-valent iron (nZVI) rapidly reacts with oxygen to produce strong oxidants capable of transforming organic contaminants in water. However,the low yield of oxidants with respect to the iron added normally limits the application of this system. Bimetallic nickel-iron nanoparticles (nNi-Fe; i.e., Ni-Fe alloy and Ni-coated Fe nanoparticles) exhibited enhanced yields of oxidants c...

We have successfully produced bimetallic PtNi alloy nanoparticles on poly (diallyldimethylammonium chloride) (PDDA)-modified graphene nanosheets (PtNi/PDDA-G) by the “one-pot” hydrothermal method. The size of PtNi alloy nanoparticles is approximately 2–5 nm. The PDDA-modified graphene nanosheets (PDDA-G) provides an anchored site for metal precursors; hence, the PtNi nanoparticles could be easi...

Nanoscale alloying and phase transformations in physical mixtures of Pd and Cu ultrafine nanoparticles are investigated in real time with in situ synchrotron-based x-ray diffraction complemented by ex situ high-resolution transmission electron microscopy. The combination of metal-support interaction and reactive/non-reactive environment was found to determine the thermal evolution and ultimate ...

In the quest for environmental remediation which involves eco-friendly synthetic routes, we herein report synthesis and modeling of silver nanoparticles (Ag NPs) and silver/nickel allied bimetallic nanoparticles (Ag/Ni NPs) using plant-extract reduction method. Secondary metabolites in the leaf extract of Canna indica acted as reducing agent. Electronic transitions resulted in emergence of surf...

The effect of the surfactant on the size, polydispersity, type of size distribution and structure of nanoparticles synthesized in microemulsions has been studied by computer simulation. The model simulates the surfactant by means of two parameters: the intermicellar exchange parameter, kex, related to dimer life time, and film flexibility parameter, f, related to interdroplet channel size. One ...

We demonstrated the self-assembly of transition metal carbide nanoparticles coated with atomically thin noble metal monolayers by carburizing mixtures of noble metal salts and transition metal oxides encapsulated in removable silica templates. This approach allows for control of the final core-shell architecture, including particle size, monolayer coverage, and heterometallic composition. Carbo...

Gold nanoparticles are one of the most used nanomaterials. They are usually synthesized by the reduction of gold(III) chloride. However, the presence of halide ions in the reaction mixture is not always welcome. In some cases, these ions have detrimental influence on the morphology and structure of resulting nanoparticles. Here, we present a simple and halogen-free procedure to prepare gold nan...

Bimetallic nanoparticles display unique physical and chemical properties, including improved stability, enhanced optical or higher catalytic activity. Here, a synthetic methodology is described to obtain bimetallic heterostructures alloyed plasmonic nanocrystals through the irradiation of colloidal Au@Ag core–shell nanorods (Au@Ag NRs) with femtosecond laser pulses. Depending on energy deposite...

Bimetallic platinum-copper nanoparticles on carbon support are studied as a perspective electrochemical catalyst by anomalous small-angle X-ray scattering near the Pt absorption L3-edge. The simultaneous fitting of several diffraction patterns measured at different photon energies lead to a satisfactory agreement between experimental and model curves in the assumption of core-shell structure of...