pediatric mandibular fractures have been successfully managed in various ways. the use of a lingual splint is an option. this article presents a 4-year old boy who was treated by an alternative conservative method with a combination of an arch bar plus a lingual splint, circum-mandibular wiring and imf for the reduction, stabilization and fixation of a severely displaced bilateral man dibular b...

Nanostructured materials, such as zeolites and metal-organic frameworks, have been considered to capture CO2. However, their application has been limited largely because they exhibit poor selectivity for flue gases and low capture capacity under low pressures. We perform a high-throughput screening for selective CO2 capture from flue gases by using first principles thermodynamics. We find that ...

Transition metal (TM) embedded two-dimensional phthalocyanine (Pc) sheets have been recently synthesized in experiments [M. Abel, S. Clair, O. Ourdjini, M. Mossoyan, and L. Porte, J. Am. Chem. Soc. 133, 1203 (2010)], where the transition metal ions are uniformly distributed in porous structures, providing the possibility of capturing gas molecules. Using first principles and grand canonical Mon...

There are extensive efforts underway worldwide to develop inexpensive and practical hydrogen storage materials for the implementation of a hydrogen-based energy economy. Perhaps the most promising candidates are light metal hydrides and their complexes. Amongst these, the binary hydride of aluminium, alane (AlH3)x, is increasingly recognised as a leading candidate, satisfying most of the requir...

We study the allylic oxidation of cyclohexene with O2 under mild conditions in the presence of transition-metal catalysts. The catalysts comprise nanometric metal oxide particles supported on porous N-doped carbons (M/N:C, M=V, Cr, Fe, Co, Ni, Cu, Nb, Mo, W). Most of these metal oxides give only moderate conversions, and the majority of the products are over-oxidation products. Co/N:C and Cu/N:...

Catalytic heterogeneous hydrogenation processes arguably belong to the most valuable synthetic transformations known. Current batch reactor technology is not only time consuming and difficult to set up but also catalyst addition and filtration is hazardous. Because of the aromatic character of many substrates, hydrogenation often requires the use of significant hydrogen pressures in combination...

Reaction of CuCl(2) x 2 H(2)O with 1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene (H(3)BTTri) in DMF at 100 degrees C generates the metal-organic framework H(3)[(Cu(4)Cl)(3)(BTTri)(8)(DMF)(12)] x 7 DMF x 76 H(2)O (1-DMF). The sodalite-type structure of the framework consists of BTTri(3-)-linked [Cu(4)Cl](7+) square clusters in which each Cu(II) center has a terminal DMF ligand directed toward the int...

drought stress is one of the serious problems that restricted agronomic plant production worldwide. inmolecular level, the harmful effect of drought stress is mostly caused by producing of large amount ofreactive oxygen species (ros). catalase and metallothionein genes have a crucial role to mope the hydrogenperoxide (h2o2) resulting reducing oxidative damage. in this research the gene expressi...

We report on high resolution Echelle spectroscopy of 20 giant stars in the Galactic old open clusters NGC 6791 obtained with Hydra at the WIYN telescope. High precision radial velocity allow us to isolate 15 bona fide cluster members. From 10 of them we derive a global [M/H]=+0.39±0.05. We therefore confirm that NGC 6791 is extremely metal rich, exhibits a few marginally sub-solar abundance rat...