ABSTRACT In this study, an optimized vortex-assisted method for rapid screening of oil content in Jatropha curcas L. (Jatropha) seeds is described. A 24-1IV fractional factorial design was employed to study the influence vortex stirring rate, sample:solvent ratio, extraction time, and number cycles efficiency. Gas chromatography-mass spectrometry (GC-MS) used identification fatty acids. The mos...

The direct dehydrogenation of butane (BDH) is emerging as an attractive on-purpose technology for the production 1,3-butadine. However, its product yield hindered by high rate carbon deposition associated to temperature required highly endothermic reaction. In this work, we evaluated use H2-selective membrane reactor, increase process at milder operating conditions. novel proposed reactor (MR)-...

Peel-and-stick process, or water-assisted transfer printing (WTP), represents an emerging process for transferring fully fabricated thin-film electronic devices with high yield and fidelity from a SiO2/Si wafer to various non-Si based substrates, including papers, plastics and polymers. This study illustrates that the fundamental working principle of the peel-and-stick process is based on the w...

A combination of computational and experimental methods was carried out to elucidate the mechanism of palladium-catalyzed water-assisted benzylic C-H amination with N-fluorobenzenesulfonimide (NFSI), which involved the oxidative addition of Pd(II) to Pd(IV)-species as a rate-limiting step, followed by water-assisted concerted metalation-deprotonation (CMD) of the Pd(IV) complex and water-assist...

N accessible shale deposits have dramatically increased global gas reserves and are touted as a bridge to a clean energy future. For example, in the U.S., where shale gas is projected to comprise 49% of national natural gas production by 2035, proponents argue that shale gas production can provide energy independence, create employment, and stimulate regional economies. Amidst this optimism, ho...

Switch on the weather forecast any evening and one is left in no doubt as to the importance of water in the Earth’s atmosphere: will the water be gaseous (humidity), liquid (clouds, rain), solid (snow, ice or hail) or taken up by aerosol (haze) particles? The long-term role of water in our climate, and of course any change in our climate, is no less profound. The water vapour is both the domina...

Domen developed a sealed water calorimeter at NIST to measure absorbed dose to water from ionizing radiation. This calorimeter exhibited anomalous behavior using water saturated with gas mixtures of H2 and O2. Using computer simulations of the radiolysis of water, we show that the observed behavior can be explained if, in the gas mixtures, the amount-of-substance of H2 and of O2 differed signif...

Natural gas storage process in aquifer, due to fluid flow behavior of gas and water in the porous medium and because of their contact with each other under reservoir conditions, faces several challenges. Therefore, there should be a clear understanding of the injected gas behavior before and after the injection into the reservoir. This research simulates the natural gas storage in aquifer by us...