This study was performed to investigate the role of reactive oxygen species and inducible nitric oxide (NO) synthase (iNOS) and cyclooxygenase-2 (COX-2) metabolites in the lipopolysaccharide effect on bradykinin-induced relaxation in middle cerebral arteries from normotensive Wistar-Kyoto (WKY) rats and spontaneously hypertensive rats (SHRs). LPS exposure (10 microg/ml for 1-5 h) reduced bradyk...

Of the total one-way chloride fluxes (approximately 1.4 meq/liter cell water X min) in steady state human polymorphonuclear leukocytes bathed in 148 mM Cl media, approximately 70% behaves as self-exchange mediated by a nonselective anion carrier that is not inhibited by stilbene disulfonates. Five properties of this carrier-mediated exchange were investigated: substrate saturation is seen with ...

Zn-Al layered double hydroxide (LDH) nanoparticles with carbonate as the charge balancing anion in the interlayer space were synthesized using co-precipitation method. Then, the carbonate base Zn-Al LDH nanoparticles were doped with phosphate ion via anion-exchange reaction to synthesize Zn-Al-[PO43-]-[CO32-]. The structure and composition were characterized by X-ray diffraction (XRD), Fourier ...

Continuous wave (cw) X-band EPR spectra at approximately 90 K were obtained for iron-transferrin-anion complexes with 18 anions. Each anion had a carboxylate group and at least one other polar moiety. As the second polar group was varied from hydroxyl to carbonyl to amine to carboxylate, the EPR spectra changed from a dominant signal at g' approximately 4.3 with a second smaller peak at g' appr...

The synthesis, X-ray crystal structures and anion recognition properties of two receptors containing thiazine-1,1-dioxide heterocycles as hydrogen bond donating subunits are reported. The newly synthesized receptors display much different anion selectivities in acetone-d₆ than N,N'-diphenyl-1,3-disulfonamidobenzene that was used as a comparison. The selectivity exhibited by one of the new recep...

The pH and buffer capacity of two soils increased or remained constant after incubation with different amounts of plant material (lucerne chaff) at field capacity and when air dry. For both soils, the pH changes were greater at field capacity, whereas the buffer capacities were independent of the water treatments. The pH changes observed could be explained in terms of the organic anion concentr...

Recent discovery of HfO2-based and nitride-based ferroelectrics that are compatible to the semiconductor manufacturing process have revitalized field ferroelectric-based nanoelectronics. Guided by a simple design principle charge compensation density functional theory calculations, we discover HfO2-like mixed-anion materials, TaON NbON, can crystallize in polar Pca21 phase with strong thermodyn...

In this review we cover recent developments in fluorescent and colorimetric anion sensors. These systems employ a range of different non-covalent interactions including hydrogen- halogen-bonding, Lewis acidic boron-based sensors, metal-based charged systems, compounds that use anion-pi to stabilise complexes, photoswitchable the excimers molecular logic gates sensing. Recent anion-selective che...