نتایج جستجو برای: aminophenol isomers
تعداد نتایج: 10811 فیلتر نتایج به سال:
Chlorogenic acid is a well-known antioxidant and has more isomers according to the difference in binding location and number of caffeic on quinic acid. In this study, we investigated and compared the profiles of antioxidant and DNA-protective activities of chlorogenic acid isomers including three caffeoylquinic acid isomers (3-O-caffeoylquinic acid, 3-CQA; 4-O-caffeoylquinic acid, 4-CQA; and 5-...
To evaluate the importance of the conformation of amphetamine in eliciting its various central nervous system effects, the conformationally defined analogs of amphetamine. In this series of isomeric amines, the exo-2 and anti-9 isomers resemble the fully extended conformation of amphetamine, whereas the endo-2 and syn-9 isomers resemble the folded conformation. The exo-2 and anti-9 isomers were...
The isoprenoid donor for protein geranylgeranylation reactions, geranylgeranyl diphosphate (GGDP), is the product of the enzyme GGDP synthase (GGDPS) that condenses farnesyl diphosphate (FDP) and isopentenyl pyrophosphate. GGDPS inhibition is of interest from a therapeutic perspective for multiple myeloma because we have shown that targeting Rab GTPase geranylgeranylation impairs monoclonal pro...
We have studied the kinetics of trans to cis isomerization under the illumination of ultraviolet light, in the Langmuir monolayer of mesogenic azobenzene dimer, bis-[5-( 4' -n-dodecyloxy benzoyloxy)-2-( 4''-methylphenylazo)phenyl] adipate, at an air-water interface. We find that the trans to cis isomerization reaction of the molecules in the monolayer shows deviation from the first-order kineti...
4-Methylcyclophosphamide was synthesized and separated into cis and trans isomers by column chromatography. Isolation of these isomers permitted individual evaluation against murine leukemia L1210 in vivo and assessment of possible differences in antileukemic activity. Results indicate no appreciable difference in activity of the isomers, suggesting essentially equal facility for activation by ...
A rapid method for characterization and online detection of surfactin isomers was developed based on HPLC-MS(n) (n = 1, 2, 3) analyses, and many surfactin isomers were detected and characterized from the bioactive fraction of the mangrove bacterium Bacillus sp. Inhibitory activities of surfactin isomers on the overproduction of nitric oxide and the release of TNF-α and IL-6 in LPS-induced macro...
A novel metal complexes Cu (II), Co Cd Ru (III) from azo ligand 5-((2-(1H-indol-2-yl) ethyl) diazinyl)-2-aminophenol were synthesized by simple substitution of tryptamine with 2-aminophenol. Structures all the newly compounds characterized FT IR, UV-Vis, Mass spectroscopyand elemental analysis. In addition measurements magnetic moments, molar conductance and atomic absorption. Then study their ...
The nitrite ® nitro isomerization in nitritopentaamine cobalt (III) halides has been known. In this paper, the effect of the size of the counter ions (noncoordinated groups) on the rate of isomerization in nitritopentaamine cobalt (III) halides, is reported. The rate of isomerization is decreased by increasing the size of the counter ions. This decrease is explained on the...
Styrene 7,8-oxide, which reacts preferentially at the N-7 position of guanine, yielded two pairs of diastereomers 7-(1'-hydroxy-2'-phenylethyl)-dGMP (the alpha-isomer) and 7-(2-hydroxy-2-phenylethyl)-dGMP (the beta-isomer) on reaction with deoxyguanosine-3'-monophosphate (3'-dGMP). The alpha- and beta-isomers were formed in the ratio 32:68. T4 polynucleotide kinase preferentially mediated label...
two possible isomers of some 1,3-diaryl-h-benzo[f]chromene have been studied using density functional theory. structures of e1 and e2 isomers were optimized at the b3lyp and mp2 levels with different basis sets. the total electronic energies show that e2 isomer is about 3-5 kcal/mol more stable than e1 isomer and this energy difference is attributed to the planarity of heterocyclic ring and mor...
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