A new Ir(III)-NHC catalyst is reported that shows remarkable activity in the N-alkylation of unprotected amino acids. The catalytic system gives excellent selectivity toward monoalkylated α-amino acids and a high degree retention stereochemistry. wide range nonnatural have been prepared. These compounds represent an array building blocks could be used for direct synthesis peptidomimetics. amino...

objective: the objective of this study was to investigate the pathological alterations of methionine for chicken embryo.in recent years, amino acids are used in veterinary medicine for many purposes. they injected into hatching eggs to increase chick body weight and performance at hatch, but the adverse effects of amino acids have always been a major concern. there is scant information availabl...

objective: in recent years, amino acids are used in veterinary medicine for many purposes. they injected into hatching eggs to increase chick body weight and performance at hatch, but the adverse effects of amino acids have always been a major concern. there is scant information available about the pathological alterations of amino acids in the chicken embryonated eggs. the objective of this st...

a total of 1440 arian chicks were used in this study to determine the effects of diet formulation methods on performance and blood parameters of arian chicks. eight diets were arranged in a 2×2×2 factorial design with 2 methods of energy expression (apparent (amen) and true (tmen) metabolizable energy corrected to n equilibrium), 2 methods of amino acids content of feeds (total (taaf) and diges...

biofilm formation in bacteria is an important survival strategy. biofilm of probiotic bacillus subtilis consist of long chains of cells that are covered by a polymeric matrix of exopolysaccharides. this bacterium is known as one of the most effective biocontrol agents against plant pathogens and has a high ability in biofilm formation. this study was aimed to investigate the effect of some envi...

Key words palladium catalysis - allylation amino acids peptides

A simple and efficient one-pot, three-component Strecker reaction of protected amino acids, aromatic aldehydes, and trimethylsilyl cyanide has been developed for the synthesis of chiral α-amino nitriles. The reaction was carried out in the presence of catalytic amount of phosphotungstic acid (H3[P(W3O10)4]) as an environmentally friendly cata...