The presence of H2O vapour in an oxidizing environment can increase the critical aluminium concentration, NAl ∗ , required to establish a passivating Al2O3 scale in multicomponent alumina-forming alloys. This work used AlxFeyNi1-x-y composition spread alloy film combinatorial libraries to determine NAl ∗ (x, y) continuously across AlxFeyNi1-x-y composition space (x = 0 → 1, y = 0 → [1-x]) in a ...