Nanoscale bimetallic Ni/Fe particles were synthesized from the reaction of sodium borohydride (NaBH4) with reduction of Ni2+ and Fe2+ in aqueous solution. The obtained Ni/Fe particles were characterized by TEM (transmission electron microscope), XRD (X-ray diffractometer), and N2-BET. The dechlorination activity of the Ni/Fe was investigated using p-chlorophenol (p-CP) as a probe agent. Results...

introduction the shahrestanak mn deposit is located in southern qom province, 12 km southwest of the city of kahak. based on geological-structural divisions of iran, the deposit belongs to central volcanic belt or urumieh-dokhtar zone. the venarch deposit is one the most important known manganese deposits in iran. the sharestanak and venarch deposits are spatially and temporally related to each...

A crystal structure of the anaerobic Ni-Fe-S carbon monoxide dehydrogenase (CODH) from Rhodospirillum rubrum has been determined to 2.8-A resolution. The CODH family, for which the R. rubrum enzyme is the prototype, catalyzes the biological oxidation of CO at an unusual Ni-Fe-S cluster called the C-cluster. The Ni-Fe-S C-cluster contains a mononuclear site and a four-metal cubane. Surprisingly,...

Treatment of [NEt4][(pzTp)Fe(III)(CN)3] (1) with Ni(II)(OTf)2 (OTf = trifluoromethanesulfonate) and 1,5,8,12-tetraazadodecane (L) affords {[(pzTp)Fe(III)(CN)3]2[Ni(II)L]} x 1/2MeOH (2), while 2,2'-bipyridine (bipy) affords {[(pzTp)Fe(III)(CN)3]2[Ni(II)(bipy)2]} x 2 H2O (3). Magnetic measurements indicate that 2 and 3 have S = 2 ground states and that 3 exhibits slow relaxation of the magnetizat...

The divalent transition-metal cations Fe, Co, and Ni were used to test the hypothesis that Mn ions pass through calcium channels because Mn ions have a relatively low energy of hydration. The test ions were applied to the bath and comparisons were made of their effects on Ca or Mn spikes elicited from myoepithelial cells of the proventriculus of the polychaete worm Syllis spongiphila. Control e...

We have derived elemental abundances of O, Ni as well as for a number of s-elements for 47 G and K dwarf, with Me/H]> 0:1 dex. The selection of stars was based on their kinematics as well as on their uvby ?-photometry. One sample of stars on rather eccentric orbits traces the chemical evolution interior to the solar orbit and another, on circular orbits, the evolution around the solar orbit. A ...

A poly(amine ester) dendrimer with naphthyl units (G1N6) has been synthesized as a fluorescent chemosensor for metal ions. We investigated the metal-ion recognition of G1N6 by adding each of Ag(+), Al(3+), Ba(2+), Ca(2+), Cd(2+), Co(2+), Cu(2+), Fe(3+), Mg(2+), Ni(2+), and Zn(2+) in acetonitrile solution. Large changes were observed in the fluorescence spectra of G1N6 upon the addition of Al(3+...

As an analogy to nickel-based superalloys, ferritic superalloys based on Fe-Al-Cr-Ni-Ti are proposed for high-temperature applications, especially for fossil-energy power systems. Integrated computational tools will be employed to investigate thermodynamic, kinetic, and meso-scale properties of the proposed alloy systems. Meanwhile, selected microstructural attributes in representative model fe...