نتایج جستجو برای: acidic solvents
تعداد نتایج: 78820 فیلتر نتایج به سال:
background organic solvents are widely used in cell biology experiments. despite increasing the solubility, they have some moderate toxic effects. therefore, selecting the appropriate solvent along with the use of suitable concentration insures the accuracy and reliability of experimental results. objectives the current study aimed to examine the cytotoxic effects of some organic solvents on va...
background: organic acids refer to a family of compounds that are intermediates in a variety of metabolic pathways. many organic acids are present in urine from clinically normal individuals. elevated levels of urine organic acids cause to the organic acidurias, disorders in which some metabolic pathways in organic acid metabolism are blocked. the present work identified major and minor urinary...
some of the adamantane properties were calculated in this study. chemical shift, free energy ofsolvation, free energy of cavity formation, henry's law constant, and other properties ofadamantane in dry phase, three solvents and three temperatures have been calculated with abinitio method base on density functional theory (dft) at b3lyp/6-31g, b31yp/6-31g*, b3lyp/6-31+g* and b3lyp/6-31++g** leve...
tris(3-bromo-acetylacetonato) chromium(iii) as an inert and very stable complex with a good leaving group was synthesized using as-prepared cr(acetylacetonate)3. highly ordered nanoporous silica (lus-1), with some great features, was functionalized with 3-aminopropyltriethoxysilane. then the as-prepared product was modified with tris(3-bromo-acetylacetonato) chromium(iii) under mild reaction co...
Baker’s yeast catalyzes the asymmetric reduction of prochiral ketones in water and in various organic solvents. The reaction in water, which is the first solvent of choice for bio-reactions, led to a high product yield and enantiomeric excess, but the low miscibility of organic molecules in water resulted in lower conversions when more hydrophobic ketones were used. Petroleum-based solvents suc...
Organic solvents are chemically different compounds with one common feature: They dissolve fats, oils, resins, cellulose, acetate, and cellulose nitrate, which makes them widely used in industry. Most often organic solvents are used in paint and lacquer industries, in production of pesticides, explosives, plastic, rubber, cellulose, air conditioners, in pharmaceutical industry, and in leather i...
a variety of alcohols readily add to 3,4-dihydro-2h-pyran under solvent free conditions in the presence of catalytic amount of acidic ionic liquid [et3n(ch2)4so3h][ots] to afford the corresponding tetrahydropyranyl ethers in good to excellent yields at room temperature. the use of this procedure allows easy separation of the desired products from ionic liquid and recycling the ionic liquid. som...
background: induced pluripotent stem cells (ipscs) can be obtained from autologous cells for therapeutic purposes. so, far, many studies have been done to produce induced pluripotent cells by transferring specific pluripotency genes using different methods. in this study, pluripotency gene expression induced by external stresses was assessed in cord blood mononuclear cells. methods: in this exp...
introduction: hearing loss is one of the most common occupational diseases. in most workplaces, workers are exposed to noise and solvents simultaneously, so the potential risk of hearing loss due to solvents may be attributed to noise. in this study we aimed to assess the effect of exposure to mixed aromatic solvents on hearing in the absence of exposure to hazardous noise. materials and met...
Subtilisin and alpha-chymotrypsin vigorously act as catalysts in a variety of dry organic solvents. Enzymatic transesterifications in organic solvents follow Michaelis-Menten kinetics, and the values of V/Km roughly correlate with solvent's hydrophobicity. The amount of water required by chymotrypsin and subtilisin for catalysis in organic solvents is much less than needed to form a monolayer o...
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