A variety of 4-phosphinylpyrrolidin-3-ones was prepared via a [3+2] cycloaddition between aryl aldonitrones and phosphinylallenes. The products were isolated as unique 4,5-trans diastereomers, in yields up to 80% over 23 examples. In the case chiral racemic allenes, 2:1 4:1 moderate 2,5-diastereoselectivity observed. Under reaction conditions, cycloadducts directly undergo rearrangement afford ...

In this study some new compounds have been prepared including thereaction of diazoium salt 1,4-phenylenediamine with 2-mercaptobenzaldehyde at (0-5)0C[F1]. Then Schiff bases [F2-F6] werethen synthesized through the reaction compound [F1] withsubstituteds aniline in absolute ethanol, and were convertedinto 2,3 - dihyroquinazolin 4(1H) one derivatives [F7-F11] by 2-amino benzoic acid ethanol. The...