Biobased monomers derived from castor oil as well as from limonene suitable for thiol–ene copolymerization were synthesized. Di‐10‐undecenylether 2 was obtained via GaBr3‐catalyzed reduction of 10‐undecenyl 10‐undecenoate 1. Diene ether 2 and (R)‐limonene 5 were reacted in two steps using radical thiol–ene addition reactions to dithiol ether 4 and dithiol 7, respectively. Diene ether 2 and dith...

In this study, thiol/disulfide homeostasis in the liver tissues of high-fructose-fed rats was investigated conjunction with changes main hepatic detoxification enzyme, glutathione S-transferase (GST). Additionally, effects well-known probiotics namely Kefir, Lactobacillus helveticus, and plantarum supplementation on thiol/disulfate contents GST activity gene expression levels were analyzed. Fru...

Objectives: One of the most common emergency surgery in pediatric is due to acute appendicitis (AA). The diagnosis AA usuallymade using with clinical score signs, symptoms, and laboratory tests. But symptoms signs are not always typical, andthis situation put clinician a compelling situation. range misdiagnosis between 28-57 % 2-12 years old children.Thiol/ Disulphide homeostasis an important i...

The reactivities of the two cysteine thiol groups of calf thymus F3 histone were investigated using 5,5'-dithiobis-[2- nitrobenzoic acid], (DTNB). In isolated histone, both thiol groups were available for reaction. However, analysis of reaction profiles of native deoxyribonucleohistone, (DNH), in various solvent conditions, together with gel electrophoresis studies of DNH modified with DTNB, sh...

1. A method is described for the estimation of thiol ester groups. The thiol ester is converted into the corresponding thiol by reaction with ammonia; the thiol is then titrated amperometrically with mercuric chloride. 2. The method may be used in the presence of SH and S.S groups. The SH groups are titrated at pH3 in the presence of excess of chloride; under these conditions thiol esters do no...

1. A Sepharose-(glutathione-2-pyridyl disulphide) conjugate has been prepared. 2. Its use in a new type of chromatography, covalent chromatography by thiol-disulphide interchange, is described. 3. With this technique, papain containing 1 intact catalytic site [thiol with high reactivity towards 2,2'-dipyridyl disulphide (2-Py-S-S-2-Py) at pH4] per mol of protein is readily prepared both from dr...