Abstract Oxamates as building blocks play an important role in organic and bioorganic chemistry well coordination material sciences. In this paper, we present new fluorinated derivatives, which are synthesized from selected primary amines R F NH 2 (R =CH CF 3 , CH CHF CH(CF ) CH(CH )CF or their hydrochlorides ethyl oxalylchloride. Since oxamates can be considered 1,2 diketones, investigated pro...