نتایج جستجو برای: 1d copperi coordination polymer
تعداد نتایج: 189782 فیلتر نتایج به سال:
Crystal structures and dynamic rearrangements of one-dimensional coordination polymers with 4,4'-dipyridylsulfide (dps) have been studied. Reaction of Ni(NO(3))(2)·6H(2)O with dps in EtOH yielded [Ni(dps)(2)(NO(3))(2)] ·EtOH (1), which had channels filled with guest EtOH molecules among the four Ni(dps)(2) chains. This coordination polymer reversibly transformed the channel structure responding...
Two new neutral nano flower polymeric lead(II) coordination compounds, [Pb(tmph)(μ-SCN)₂]n (1) and [Pb(tmph)(μ-NO₃)₂]n (2), [tmph=3,4,7,8-tetramethyl-1,10-phenanthroline], have been synthesized by a sonochemical process and characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD), FT-IR spectroscopy and elemental analyses. SEM image shows the nano flower morphology f...
In the crystal structure of the title coordination polymer, {[Zn(2)(C(17)H(8)O(10))(C(3)H(7)NO)(2)]·C(3)H(7)NO}(n), the mol-ecular build-ing block (MBB), viz. {Zn(2)(CO(2))(4)(C(3)H(7)NO)(2)}, comprises two zinc atoms, each bridged by three carboxyl-ate groups. These two Zn atoms exhibit different coordination environments: a distorted coordination intermediate between trigonal-pyramidal, and s...
The reaction of select copper(II) monocarboxylates Cu(RCOO)2(H2O)x (R = C4H3O, C6H5, H; x 2, 4) with pyrazole (Hpz), carried out in protic solvents, yields mono- or dinuclear species [Cu(RCOO)2(Hpz)n]m (n 4; m 1, 2), always accompanied by tri- hexanuclear derivatives based on the triangular [Cu3(?3-OH)(?-pz)3]2+ fragment. molecular structures all isolated compounds have been established through...
We study thermal transport in a one-dimensional (1D) interacting electron gas, employing the Luttinger liquid model. Both thermal conductance and thermopower are analyzed for a pure 1D gas and with impurities. The universal ratio of electrical to thermal conductance in a Fermi liquid— the Wiedemann-Franz law—is modified, whereas the thermopower is still linear in temperature. For a single impur...
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