Reported here is an organic-cation templated 4-connected anionic boron imidazolate framework [N(CH(3))(4)][Cd(SH)(2)B(im)(4)] (ABIF-1, im = imidazolyl), which is synthesized from the reaction of the supertetrahedral Cd(10)S(4)(SPh)(12) cluster with [N(CH(3))(4)]Cl and NaB(im)(4). The work represents an important step in the expansion of boron imidazolate frameworks from neutral BIFs to anionic ...

Cathepsin D (CD) up-regulation has been associated with human malignancy and poor prognosis. Thrombin up-regulated CD mRNA and protein in eight tumor cell lines as well as in human umbilical vascular endothelial cells (HUVEC). Thrombin increased the secretion of CD by 3- to 8-fold and enhanced chemotaxis ( approximately 2-fold) in 4T1 murine mammary CA cells, which was completely inhibited with...

CD studies of the deoxyoligomer series d(pT)(n) and d(pA)(n) show increasing CD maxima for oligo (dT)'s with chain length variation from two to seven, while oligo (dA)'s exhibit a decreasing CD maximum. Concentrated solutions of NaClO(4) cause a decrease in the CD of longer oligo (dT)'s towards the CD of d(pT)(2) which is different from oligo dA's. Probably base-sugar interactions are important...

Abstract Background We aimed to assess the gene expression profiles of uninflamed small bowels in patients with Crohn’s disease (CD) identify its accompanying molecular alterations. Methods performed RNA sequencing bowel tissues obtained from 70 ileal CD, and 9 colon cancer (non-CD controls) during resection. Differentially expressed (DEG) analyses were using DESeq2. Gene set enrichment, correl...

Contrast-detail experiments were performed to optimize technique factors for the detection of low-contrast lesions using a silicon diode array full-field digital mammography (FFDM) system under the conditions of a matched average glandular dose (AGD) for different techniques. Optimization was performed for compressed breast thickness from 2 to 8 cm. FFDM results were compared to screen-film mam...

In the title complex, [Cd(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Cd atom lies on a twofold axis and adopts a square-pyramidal coordination geometry. The water mol-ecule occupies the axial site with O atoms from four different 4-chloro-benzoato ligands in the equatorial plane. Pairs of 4-chloro-benzoato ligands bridge adjacent Cd(II) ions, generating an infinite chain structure along the c axis. Par...

The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol-ecules and the N atoms of two 4,4'-bipyridine mol-ecules in an octa-hedral geometry. Bridging gives rise to chains along [101] and [-101]. The 4-hy-droxy-3-sulfonato-benzoate dianions are not connected to th...

Abstract This study reports the systematic development of cyclodextrin magnetic biocomposite for remediation 4-nitrophenol from wastewater. Magnetic was synthesized by co-precipitation Fe 2+ and 3+ in presence NaOH treated pine-cone followed cross-linking with using epichlorohydrin, achieved an optimization tool. The experiments were designed interaction between working condition variables (CM-...

In the title compound, [Cd(C(8)H(4)O(4))(C(3)H(4)N(2))(H(2)O)](n), the Cd(II) ion is seven-coordinated by five O atoms from three crystallographically independent benzene-1,3-carboxylate ligands, one N atom from the imidazole ligand and one coordinated water mol-ecule. Neighboring Cd(II) ions are bridged by the benzene-1,3-dicarboxyl-ate ligands, forming a zigzag polymeric chain structure. Thes...