Semiconductor photocatalysis has been intensively studied in recent decades for a wide variety of application such as hydrogen production from water splitting and water and air treatment. The majority of photocatalysts are, however, wide band-gap semiconductors which are active only under UV irradiation. In order to effectively utilize visible solar radiation, this thesis investigates various t...

A review is presented on the use of charged cyclodextrins (CDs) as chiral selectors in capillary electrophoresis (CE) for the separation of analytes in pharmaceutical analysis. An overview is given of theoretical models that have been developed for a better prediction of the enantiomeric resolution and for a better understanding of the separation mechanism. Several types of charged CDs have bee...

Photoelectrochemical (PEC) water splitting is a promising route for solar energy harvesting and storage, but it has been highly limited by the performance of the semiconductor photoelectrodes. Herein, we report a small molecular amine-mediated solvothermal method for synthesizing CdS nanorods. The obtained CdS nanorods are hydrophilic and can be easily dispersed in water. Furthermore, the small...

A facile route to assemble cadmium sulfide (CdS) quantum dots (QDs) uniformly on the surface of titanate nanobelts (TNBs) through electrostatic interactions is demonstrated. The photophysical properties of the resulting TNB-CdS nanostructured composite, including optical limiting properties, were studied using ultraviolet-visible absorption spectroscopy, photoluminescence spectroscopy, and the ...

We employ femtosecond transient absorption spectroscopy to get an insight into ultrafast processes occurring at the interface of type II ZnSe/CdS heterostructured nanocrystals fabricated via colloidal routes and comprising a barbell-like arrangement of ZnSe tips and CdS nanorods. Our study shows that resonant excitation of ZnSe tips results in an unprecedently fast transfer of excited electrons...

CdS nanowires (NWs) were fabricated through a facile low-temperature solvothermal method, following which CeO₂ nanoparticles were modified on the NWs. The ethanol sensing characteristics of pure CdS and decorated ones with different CeO₂ content were studied. It was found that the sensing performance of CdS was significantly improved after CeO₂ decoration. In particular, the 5 at% CeO₂/CdS comp...

Clinical decision support systems (CDS) coupled with computerized physician/provider order entry (CPOE) can improve the quality of patient care and the efficiency of hospital operations. However, they can also produce unintended consequences. Using qualitative methods, a multidisciplinary team gathered and analyzed data about the unintended consequences of CPOE, identifying nine types, and foun...

Gold@carbon dots composite nanoparticles (Au@CDs) with ultrathin carbon dot (CD) shells of ca. 2 nm were prepared by reducing HAuCl(4) with CDs at 100 °C. By adjusting the feeding mass ratio of HAuCl(4) to CDs, the average diameters of Au@CDs can be modulated from 8 to 44 nm. The suspension of Au@CDs with an average diameter of ca. 24 nm was applied as a substrate for surface enhanced Raman sca...

In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)₂. In the reaction process, Ca2+ protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdrawing groups on the CD surface are converted to electron-donating groups by the hydroxyl ions. As a res...

Processing strategies are presented for controlling junction quality as both window and absorber layer thickness are reduced in polycrystalline superstrate CdS/CdTe thin-film solar cells. High resistance In2O3 and SnO2 oxide buffer layers improve coverage of chemical bath deposited CdS and device performance with PVD CdTe, resulting in efficiencies >13.5%. A new method of CdS and Cd1-xZnxS chem...