نتایج جستجو برای: سینتیک جذبسطحی وروش dft
تعداد نتایج: 23781 فیلتر نتایج به سال:
BACKGROUND The discrete Fourier transform (DFT) is often used as a spectral estimator for analysis of complex fractionated atrial electrograms (CFAE) acquired during atrial fibrillation (AF). However, time resolution can be unsatisfactory, as the frequency resolution is proportional to rate/time interval. In this study we compared the DFT to a new spectral estimator with improved time-frequency...
one of the most common signals used for achieving high range resolution in radar is stepped-frequency signals. when a target is stationary in these radars, dft (discrete fourier transform) based processing is used to attain high range resolution profile (hrrp). however, in the case of moving target, due to spreading of the echo signal spectrum, dft based processing is not optimal and decreases ...
A strategy for filtering (or denoising) of high-pass signals embedded in an impulse (heavy tail) noise environments based on the robust DFT forms has been proposed recently. In this paper we investigate various approaches for design of the robust DFT used in this application. We consider the DFT estimates based on the: linear combination of order statistics (L-estimate), myriad, and Wilcoxon es...
A fast Fourier transform (FFT) is an efficient algorithm to compute the discrete Fourier transform (DFT) of an input vector. Efficient means that the FFT computes the DFT of an n-element vector in O(n logn) operations in contrast to the O(n2) operations required for computing the DFT by definition. FFTs exist for any vector length n and for real and higher-dimensional data. Parallel FFTs have b...
The importance of including spin-orbit interactions for the correct description of structures and vibrational frequencies of haloiodomethanes is demonstrated by density functional theory calculations with spin-orbit relativistic effective core potentials (SO-DFT). The vibrational frequencies and the molecular geometries obtained by SO-DFT calculations do not match with the experimental results ...
BACKGROUND Many patients with implanted cardioverter defibrillators (ICDs) receive adjunctive antiarrhythmic drug therapy, most commonly amiodarone or sotalol. The effects of these drugs on defibrillation energy requirements have not been previously assessed in a randomized controlled trial. METHODS AND RESULTS The Optimal Pharmacological Therapy in Cardioverter Defibrillator Patients (OPTIC)...
a theoretical study of the kinetic and mechanism of 3-aug-cope rearrangement in gas phase was performed usingdet methods at b3lyp levels of theory with 6-3114ig(d,p) bass set at 298.i5k. equilibrium moleculargeometries and harmonic vibrational frequencies of the reactant, transition state did product were calculated. then,rate constant and activation thermodynamics parameters were calculated an...
the structural stabilities, geometry and electronic properties of c24 and some its heterofullerenederivatives are compared at the b3lyp/6-311-efg**//b3lyp/6-31+g* level of theory. vibrationalfrequency calculations show that all the systems are true minima. the calculated binding energies ofheterofullerenes show c24 as the, most stable fullerenes by 9.03ev/atom. while decreasing bindingenergy in...
the acidity constants (pka) of thirty four (34) ;-substituted carboxylic acids in aqueous solution havebeen calculated using conductor-like polarizable continuum (c-pcm) solvation model. the gasphaseenergies at the density functional theory (dft-mpw1pw91) and solvation energies athartree fock (hf) are combined to estimate the pka values which are very close to the experimentalvalues where, and ...
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