This study aimed at assessing the ability of sunflower to remediate zinc (Zn) impacted soils and partitioning factors Zn in soil-plants interactions. The research method used ex situ experiments using teddy bear seeds with 8 different treatments for each. began preparation sample soil media on garden soil, seeding seeds. was carried out six months starting August - December 2020, Helianthus ann...

A series of copper(II), nickel(II) and zinc(II) dimetallic complexes were prepared and their affinities towards arsenate investigated. Indicator displacement assays (IDAs) were carried out to establish the complexes with best affinities towards arsenate. A di-zinc complex (3) was selected and its arsenate-binding abilities investigated by isothermal titration calorimetry (ITC). The X-ray crysta...

Background: The substitution of hazardous analytical reagents such as Cd with benign alternatives for chemical determination is one of the principles of green chemistry. An eco-friendly Zn reduction method for nitrate determination was developed to achieve this end. Methods: Online zinc reduction-sequential injection analysis (ZnR-SIA) protocol was developed for the determination of nitrogen (N...

From the viewpoint of x-coordinate-only arithmetic on elliptic curves, switching between the Edwards model and the Montgomery model is quasi cost-free. We use this observation to speed up Montgomery’s algorithm, reducing the complexity of a doubling step from 2M + 2S to 1M + 3S for suitably chosen curve parameters. 1 Montgomery’s algorithm Aiming for an improved performance of Lenstra’s ellipti...

In this work, we developed a method based on ultrasound-assisted emulsification microextraction (USAEME) for the determination of zinc and copper by flame atomic absorption spectrometry (FAAS). The method is based on the use of the organic solvent carbon tetrachloride (CCl4) as an extraction solvent. In order to obtain a high enrichment factor, the effect of different parameters affecting the c...

A series of novel Zn(II) complexes [Zn2(nap)4] (1), [Zn(nap)21,10-phen](2), [Zn(nap)22,9-dmphen] (3), [Zn(nap)2(2-ampy)2] (4), [Zn(nap)2(imid)2] (5), [Zn(nap)2(1,2-dmimid)2] (6) (nap = naproxen, 1,10-phen = 1,10-phenanthroline, 2,9-dmphen = 2,9-dimethyl-1,10-phenanthroline, 2-ampy = 2-aminopyridine, imid = imidazole, 1,2-dmimid = 1,2-dimethyl imidazole) were synthesized and characterized using ...

A new concept in multifunctional anticancer agents is demonstrated. Tetrakis-(diisopropyl-guanidino) zinc phthalocyanine (Zn-DIGP) exhibits excellent properties as a photodynamic therapy (PDT) agent, as well as potential anti-metastatic activities in vivo. Zn-DIGP exhibits good cellular uptake and low toxicity in the dark (EC50 > 80 μM) and is well tolerated upon its intravenous injection into ...

A V-Shaped 4-amino-1,8-napthalimide derived tetracarboxylic acid linker (L; bis-[N-(1,3-benzenedicarboxylic acid)]-9,18-methano-1,8-naphthalimide-[b,f][1,5]diazocine) comprising the Tröger's base (TB) structural motif was rationally designed and synthesised to access a nitrogen-rich fluorescent supramolecular coordination polymer. By adopting the straight forward precipitation method, a new lum...

Abstract. The asymptotic behaviour for solutions of a difference equation ∆zn = f(n, zn), where the complex-valued function f(n, z) is in some meaning close to a holomorphic function h, and of a Riccati difference equation is studied using a Lyapunov function method. The paper is motivated by papers on the asymptotic behaviour of the solutions of differential equations with complex-valued right...

Total elemental analyses of biochars presents challenges during digestion because of biochars’ high chemical recalcitrance and widely varied composition. Three biochars were chosen with contrasting properties: corn stover pyrolyzed at 300 ◦C, oak wood at 600 ◦C, and poultry manure with sawdust at 600 ◦C. Recovery of phosphorus (P), potassium (K), sulfur (S), calcium (Ca), magnesium (Mg), and zi...