Lima-Cabello E, Cuevas MJ, Garatachea N, Baldini M, Almar M, González-Gallego J. Eccentric exercise induces nitric oxide synthase expression through nuclear factorB modulation in rat skeletal muscle. J Appl Physiol 108: 575–583, 2010. First published December 31, 2009; doi:10.1152/japplphysiol.00816.2009.—This study aimed to investigate the effect of eccentric exercise on the expression of the ...

The fluorescent chiral tagging reagent, 4-(3-isothiocyanatopyrrolidin-1-yl)7-(N,N-dimethylaminosulfonyl)-2,1,3-benzoxadiazole (DBD-PyNCS), was utilized for the resolution of thiol enantiomers as diastereomeric derivatives. The reagent reacts with thiol enantiomers in the presence of pyridine to produce the corresponding dithiocarbamate diastereomers under mild reaction conditions (50 °C for 40 ...

Biferrocene bearing planar metal dithiocarbamates, namely, [M(FcCH2dtc)2] (dtc = furan-2-ylmethyldithiocarbamate, M = Cu(II) 1, Ni(II) 4; dtc = benzo[d][1,3]dioxol-5-ylmethyl dithiocarbamate, M = Cu(II) 2, Ni(II) 5; dtc = pyridin-2-ylmethyldithiocarbamate, M = Cu(II) 3, Ni(II) 6; Fc = ferrocenyl; Fe(η(5)-C5H5)(η(5)-C5H4-)), have been synthesized and characterized by microanalysis, magnetic susc...

In this paper, we introduce a novel and convenient method for the transformation of heterocyclic amides into heteocyclic thioamides. A two-step approach was applied for this transformation: Firstly, we applied a chlorination of the heterocyclic amides to afford the corresponding chloroheterocycles. Secondly, the chloroherocycles and N-cyclohexyl dithiocarbamate cyclohexylammonium salt were heat...

A dithiocarbamate chain transfer agent (CTA) based on Z-group substituted with a diphenyl amine (–NPh2) moiety is selected for the synthesis of statistical and diblock copolymers ethylene vinyl acetate via reversible addition–fragmentation polymerization. Benefiting from good growth control polyethylene (PE), poly(vinyl acetate) (PVAc), poly(ethylene-co-vinyl (EVA) achieved this CTA, linear typ...

zinc sulphate is currently used for treatment of zinc deficiency. its uptake by the body is poor, necessitating the administration of high doses. this leads to a range of unpleasant side effects. in order to increase the bioavailability of zinc, several zinc complexes have been designed and synthesized using bidentate ligands of hydroxypyranones and hydroxypyridinones. elemental analysis in eac...

Despite the globally increasing use of platinum-based cytostatic drugs in treatment several types cancer, only limited attention has been paid to developing a for contaminated liquid samples originating from hospitals, laboratories and manufacturing facilities before after their administration. In this work, we assess efficiency low-cost adsorbent material, dithiocarbamate-functionalized silica...

introduction: acute renal failure is a common consequence of sepisis due to concurrent renal ischaemia. the role of nitric oxide (no) in endotoxaemia and in ischaemic injury in the kidney is not well defined. material and methods: in this study we have used an animal model of sepsis induced by injection of bacterial lipopolysaccharide (lps) in the rat and measured renal nitric oxide by x-band e...

A review of the coordination chemistry along with structural features heavy element complexes dithiocarbimate di-anions in form [(R)C=NCS2]2− for R = CN, alkyl, and aryl are described. This class compound is far less studied compared well-explored dithiocarbamate mono-anions formulated as [R(R’)NCS2]− R/R’ H, aryl. The dominated by a S,S-chelating mode; rare examples alternative modes evident. ...