We present a modulated gradient spin-echo method (MGSE), which uses a train of sinusoidally shaped gradient pulses separated by 180-degree RF pulses. The RF pulses efficiently refocus chemical shifts and de-phasing due to susceptibility differences, resulting in undistorted, high-resolution diffusion weighted spectra. This allows for simultaneous spectral characterization of diffusion of severa...

It is well known that colloids can show phase transitions similar to the ones observed in molecular systems. Colloid-diluted and colloid-concentrated phases can coexist in thermodynamic equilibrium at certain conditions. In a previous work, the authors of this research have used this concept to study petroleum emulsions stability, applying thermodynamic perturbation theories to calculate a phas...

Emulsions have been used to boost immunogenicity of antigens since the discovery of complete Freunds adjuvant. Optimization to reduce reactogenicity of emulsion adjuvants lead to the development of oil in water emulsions based on squalene. MF59 is an oil-in-water emulsion that is a component of an approved influenza product in Europe. Currently MF59 is manufactured from squalene derived from an...

Mechanism of the absorption of drugs from oil in water emulsions was studied in the rat large intestine. Synthesized esters of fatty acids and phthalic acid-0.1% Polysorbate 80 was chosen as the emulsion system, the oil/water volume ratio was varied from 0 to 1, and the absorption from emulsions of sulfapyridine, salicylamide, and of acetanilide was investigated using in situ recirculation and ...

A collaborative study was conducted to test a method developed to distinguish between adequately and inadequately preserved cosmetic formulations. Nineteen laboratories participated in the study. Samples tested included shampoos, hair conditioners, oil-in-water emulsions, and water-in-oil-emulsions. Triplicate samples of 4 adequately preserved and 4 inadequately preserved cosmetic products were...

Beverage emulsions are systems that are composed of two liquids including oil and water which are prepared by homogenizing oil phase in an acidic aqueous phase. They must be stable in both concentrated and diluted form for a period of 6-12 months upon standing at room temperature. Two immiscible phases contained systems are thermodynamically unstable. In other words, they are vulnerable to brea...

Emulsion droplet sizing is an essential measurement requirement of a very broad range of industries including food, pharmaceuticals, personal care products, agrochemicals and crude oil dispersions. Nuclear magnetic resonance (NMR), courtesy of its ability to measure restricted self-diffusion via application of pulsed field magnetic field gradients (PFG), is able to readily measure emulsion drop...

Vertically-aligned multi-walled carbon nanotubes (CNTs) were grown on stainless steel (SS) mesh by thermal chemical vapor deposition with a diffusion barrier of Al2O3 film. These three-dimensional porous structures (SS-CNT meshes) were found to be superhydrophobic and superoleophilic. Water advancing contact angles of 145–150 were determined for these SS-CNT meshes in air and oil (gasoline, iso...