We report the synthesis of a water-compatible bis-glycosyl diarylethene using click chemistry that undergoes photochromism and functions as a molecular logic gate.

Arsenic contamination of groundwater is a problem worldwide, and the Terai Basin in the southern plains of Nepal is no exception. The Department of Water Supply and Sanitation of Nepal, with assistance from the World Health Organization (WHO), surveyed three districts of eastern Terai for the first time in 1999, and found that arsenic concentration exceeded the 10 ppb guideline recommended by W...

Recharge events that deliver electron acceptors such as O2, NO3, SO4, and Fe3+ to anaerobic, contaminated aquifers are likely important for natural attenuation processes. However, the specific influence of recharge on (bio)geochemical processes in ground water systems is not well understood. The impact of a moderate-sized recharge event on ground water chemistry was evaluated at a shallow, sand...

Although perovskite oxides hold promise in applications ranging from solid oxide fuel cells to catalysts, their surface chemistry is poorly understood at the molecular level. Here we follow the formation of the first monolayer of water at the (001) surfaces of Sr(n+1)Ru(n)O3(n+1) (n = 1, 2) using low-temperature scanning tunnelling microscopy, X-ray photoelectron spectroscopy, and density funct...

A detailed in situ infrared spectroscopy analysis of single layer and multilayered graphene oxide (GO) thin films reveals that the normalized infrared absorption in the carbonyl region is substantially higher in multilayered GO upon mild annealing. These results highlight the fact that the reduction chemistry of multilayered GO is dramatically different from the single layer GO due to the prese...

Water contamination is generally considered to be detrimental to the performance of aprotic lithium-air batteries, whereas this view is challenged by recent contrasting observations. This has provoked a range of discussions on the role of water and its impact on batteries. In this work, a distinct battery chemistry that prevails in water-contaminated aprotic lithium-oxygen batteries is revealed...

The membrane fouling index, widely used in the reverse osmosis (RO) membrane industry, is developed mainly to assess the fouling potential of particulate matter. However, the fouling potential by organic matter should also be accurately evaluated as the productivity loss by organic fouling is often more severe than particle fouling, despite its low concentration in feed water. This study was pe...

Combining the synoptic mass balance approach with principal components analysis (PCA) can be an effective method for discretising the chemistry of inflows and source areas in watersheds where contamination is diffuse in nature and/or complicated by groundwater interactions. This paper presents a field-scale study in which synoptic sampling and PCA are employed in a mineralized watershed (Lion C...